P3HT/PCBM bulk heterojunction solar cells: Relation between morphology and electro-optical characteristics

被引：336

作者：

Vanlaeke, P.

Swinnen, A.

Haeldermans, I.

Vanhoyland, G.

Aernouts, T.

Cheyns, D.

Deibel, C.

D'Haen, J.

Heremans, P.

Poortmans, J.

Manca, J. V.

机构：

[1] IMEC VZW, Div MCP, B-3001 Louvain, Belgium

[2] IMEC VZW, Div IMOMEC, B-3001 Louvain, Belgium

[3] Univ Hasselt, Inst Mat Onderezoek, B-3590 Diepenbeek, Belgium

来源：

SOLAR ENERGY MATERIALS AND SOLAR CELLS | 2006年 / 90卷 / 14期

关键词：

bulk heterojunction organic solar cells; polythiophene; morphology; crystallization; mobility;

D O I：

10.1016/j.solmat.2006.02.010

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

The performance of organic solar cells based on the blend of regioregular poly(3-hexylthiophene) (P3HT) and phenyl-C61-butyric acid methyl ester (PCBM) is strongly influenced by blend composition and thermal annealing conditions. X-ray diffraction (XRD) and Transmission Electron Microscopy (TEM) diffraction measurements show that in the considered blends, ordering of P3HT plays a key role in understanding the PV-performance. It is demonstrated that the natural tendency of regioregular P3HT to crystallize is disturbed by the addition of PCBM. Annealing however improves the crystallinity, explaining the observed spectral broadening and is also resulting in a higher mobility of the holes in P3HT. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：2150 / 2158

页数：9

共 50 条

[1] Nanostructured morphology of P3HT:PCBM bulk heterojunction solar cells
Kalita, Golap
Masahiro, Matsushima
Koichi, Wakita
Umeno, Masayoshi
SOLID-STATE ELECTRONICS, 2010, 54 (04) : 447 - 451
[2] Effect of Trace Solvent on the Morphology of P3HT:PCBM Bulk Heterojunction Solar Cells
Chang, Lilian
Lademann, Hans W. A.
Bonekamp, Joerg-Bernd
Meerholz, Klaus
Moule, Adam J.
ADVANCED FUNCTIONAL MATERIALS, 2011, 21 (10) : 1779 - 1787
[3] Effect of polydispersity on the bulk-heterojunction morphology of P3HT:PCBM solar cells
Munshi, Joydeep
Ghumman, Umar Farooq
Iyer, Akshay
Dulal, Rabindra
Chen, Wei
Chien, TeYu
Balasubramanian, Ganesh
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2019, 57 (14) : 895 - 903
[4] Elasto-morphology of P3HT:PCBM bulk heterojunction organic solar cells
Munshi, Joydeep
Chien, TeYu
Chen, Wei
Balasubramanian, Ganesh
SOFT MATTER, 2020, 16 (29) : 6743 - 6751
[5] Bulk and contact resistance in P3HT:PCBM heterojunction solar cells
Shen, Yang
Li, Kejia
Majumdar, Nabanita
Campbell, Joe C.
Gupta, Mool C.
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2011, 95 (08) : 2314 - 2317
[6] Solution Aging Effects on the Performance and Morphology of P3HT: PCBM Bulk Heterojunction Solar Cells
Yu, Fei
Kuppa, Vikram K.
NANO LIFE, 2015, 5 (04)
[7] The use of nanofibers of P3HT in Bulk HeteroJunction Solar Cells: The effect of order and morphology on the performance of P3HT:PCBM blends
Vanderzande, Dirk J. M.
Oosterbaan, Wibren D.
Vrindts, Veerle
Bertho, Sabine
Bolsee, Jean Christophe
Gadisa, Abay
Vandewal, Koen
Manca, Jean
Lutsen, Laurence
Cleij, Thomas J.
D'Haen, Jan
Zhao, Jun
Van Assche, Guy
Van Mele, Bruno
ORGANIC PHOTOVOLTAICS X, 2009, 7416
[8] Electrodes for GaOHPc:PCBM/P3HT:PCBM bulk heterojunction solar cell
Kaulachs, I.
Muzikante, I.
Gerca, L.
Shlihta, G.
Shipkovs, P.
Grehovs, V.
Kalnachs, J.
Roze, M.
Rozite, G.
Ivanova, A.
CHEMICAL PHYSICS, 2012, 405 : 46 - 51
[9] Transparent back contacts for P3HT:PCBM bulk heterojunction solar cells
Sendova-Vassileva, M.
Dikov, H.
Popkirov, G.
Lazarova, E.
Gancheva, V.
Grancharov, G.
Tsocheva, D.
Mokreva, P.
Vitanov, P.
18TH INTERNATIONAL SUMMER SCHOOL ON VACUUM, ELECTRON AND ION TECHNOLOGIES (VEIT2013), 2014, 514
[10] Influence of crystallizable solvent on the morphology and performance of P3HT:PCBM bulk-heterojunction solar cells
Keawprajak, Anusit
Piyakulawat, Phimwipha
Klamchuen, Annop
Iamraksa, Phansak
Asawapirom, Udom
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2010, 94 (03) : 531 - 536

← 1 2 3 4 5 →