NHC-Catalyzed Annulation of Enals to 2,4-Dien-1-ones: Efficient Diastereoselective Synthesis of 1,3-Diaryl-4-styrenyl Cyclopentenes

被引：6
|
作者：
Sinu, C. R. [1 ]
Padmaja, D. V. M. [1 ]
Jini, P. [1 ]
Lakshmi, K. C. Seetha [1 ]
Nair, V. [1 ]
机构：
[1] Natl Inst Interdisciplinary Sci & Technol CSIR, Organ Chem Sect, Trivandrum 695019, Kerala, India
来源：
SYNLETT | 2013年 / 24卷 / 13期
关键词：
NHC; catalysis; homoenolate; annulation; cyclopentene; N-HETEROCYCLIC CARBENE; STEREOSELECTIVE-SYNTHESIS; HOMOENOLATE ADDITIONS; ASYMMETRIC-SYNTHESIS; ALDEHYDES; ELECTROPHILES; CHALCONES; KETIMINES; UMPOLUNG;
D O I：
10.1055/s-0033-1339308
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Nucleophilic heterocyclic carbene (NHC)-catalyzed annulation strategy has been utilized for the efficient synthesis of styrenyl-substituted cyclopentenes from 2,4-dienones.
引用
收藏
页码：1671 / 1674
页数：4
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