Template synthesis and X-ray crystal structures of 15-membered unsymmetric monobenzotetraazaannulene nickel(II) complexes

被引：2
|
作者：
Kim, Eunhee
Lee, Hyosun [1 ]
机构：
[1] Kyungpook Natl Univ, Dept Chem, Daegu City 702701, South Korea
来源：
INORGANICA CHIMICA ACTA | 2013年 / 399卷
基金：
新加坡国家研究基金会;
关键词：
Benzotetraaza[15]annulene; Substituted benzotetraaza[15]annulene; Template synthesis; Unsymmetric monobenzotetraazaannulene nickel(II) complex; SULFUR-CONTAINING LIGANDS; MOLECULAR-STRUCTURE; MACROCYCLIC LIGAND; COORDINATION CHEMISTRY; BENZON(4) MACROCYCLES; COPPER(II) COMPLEXES; NI(II) COMPLEXES; DERIVATIVES; TETRAAZAANNULENES; BENZOYLATION;
D O I：
10.1016/j.ica.2012.12.041
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
New nickel(II) complexes A and B having macrocyclic ligands 4,10-dimethyl-2,12-diphenyl-1,5,9,13-dimethylbenzotetraazacyclo[15]tetradecine and 4,10-dimethyl-2,12-diphenyl-1,5,9,13-nitrobenzotetraazacyclo[15]tetradecine, respectively, have been synthesized and characterized by spectroscopic methods, including single-crystal X-ray diffraction. The nickel and four nitrogen atoms in both of the unsymmetrical tetraaza[15]annulene-ligated complexes have a slightly distorted square-planar arrangement rather than a square-pyramidal one, despite ring strain from coordination with the propylenediamine group. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：62 / 66
页数：5
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