Molecularly imprinted polymer based on multiwalled carbon nanotubes for ribavirin recognition

被引:25
|
作者
Xu, Li [1 ]
Xu, Zhi-feng [2 ]
机构
[1] S China Agr Univ, Coll Sci, Inst Biomat, Guangzhou 510642, Guangdong, Peoples R China
[2] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China
基金
中国国家自然科学基金;
关键词
Molecular imprinting technology; Multiwalled carbon nanotubes; Ribavirin; Molecule recognition; DIFFERENTIAL-PULSE VOLTAMMETRY; SOLID-PHASE EXTRACTION; FUNCTIONAL MONOMER; BETA-CYCLODEXTRIN; SENSOR SYSTEM; HERBICIDES; CATALYSIS; WATER;
D O I
10.1007/s10965-012-9942-1
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Molecularly imprinted polymers on the surface of multiwalled carbon nanotubes (MWNTs) have been developed for selective recognition for Ribavirin. The composites (MWNTs/MIPs) were prepared by using Ribavirin as the template molecule, acrylamide (AAM) as the functional monomer, N, N-methylenebisacrylamide (NNMBA) as the cross-linker. MWNTs/MIPs obtained were characterized by fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and thermogravimetric analysis (TGA). The properties such as adsorption dynamics, special binding, and the selective recognition ability were evaluated. The adsorption equilibrium was arrived in about 4 h which indicated that the adsorption kinetic was comparatively fast. The results of binding and selectivity experiments showed that the MWNTs/MIPs could bind the template molecule selectively in aqueous media.
引用
收藏
页数:6
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