Selective Direct N-Alkylation of Amines with Alcohols using Iron(III) Phthalocyanine Chloride under Solvent-Free Conditions

被引：15

作者：

Minakawa, Maki ^{[1
]}

Okubo, Masataka ^{[1
]}

Kawatsura, Motoi ^{[1
]}

机构：

[1] Nihon Univ, Coll Humanities & Sci, Dept Chem, Setagaya Ku, Tokyo 1568550, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2015年 / 88卷 / 12期

关键词：

IRIDIUM-CATALYZED ALKYLATION; DEHYDRATIVE ALKYLATION; HETEROCYCLIC CARBENE; RECYCLABLE CATALYST; HIGHLY EFFICIENT; COMPLEXES; RUTHENIUM; NITROARENES; AMINATION; AMMONIA;

D O I：

10.1246/bcsj.20150217

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Direct N-alkylation of amines with alcohols in the presence of iron(III) phthalocyanine chloride as a catalyst in solvent-free conditions under microwave irradiation afforded the corresponding N-alkylamines in moderate to high yield with excellent selectivity.

引用

页码：1680 / 1682

页数：3

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