Sub-part-per-billion monitoring of nitric oxide by use of wavelength modulation spectroscopy in combination with a thermoelectrically cooled, continuous-wave quantum cascade laser

被引:52
作者
Moeskops, BWM [1 ]
Cristescu, SM [1 ]
Harren, FJM [1 ]
机构
[1] Radboud Univ Nijmegen, Inst Mol & Mat, Dept Mol & Laser Phys, NL-6500 GL Nijmegen, Netherlands
关键词
D O I
10.1364/OL.31.000823
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
We used a thermoelectrically cooled, continuous-wave, quantum cascade laser operating between 1847 and 1854 cm(-1) in combination with wavelength modulation spectroscopy for the detection of nitric oxide (NO) at the sub-part-per-billion by volume (ppbv) level. The laser emission overlaps the P-7.5 doublet of NO centered around 1850.18 cm(-1). Using an astigmatic multiple-pass absorption cell with an optical path length of 76 m, we achieved a detection limit of 0.2 ppbv at 1.0 kPa, with a total acquisition time of 30 s. The corresponding minimal detectable absorption is 8.8 X 10(-9) cm(-1) Hz(-1/2). (c) 2006 Optical Society of America.
引用
收藏
页码:823 / 825
页数:3
相关论文
共 14 条
[1]   Mid-infrared quantum cascade laser based off-axis integrated cavity output spectroscopy for biogenic nitric oxide detection [J].
Bakhirkin, YA ;
Kosterev, AA ;
Roller, C ;
Curl, RF ;
Tittel, FK .
APPLIED OPTICS, 2004, 43 (11) :2257-2266
[2]   Room-temperature, continuous-wave, single-mode quantum-cascade lasers at λ≃5.4 μm -: art. no. 041109 [J].
Blaser, S ;
Yarekha, DA ;
Hvozdara, L ;
Bonetti, Y ;
Muller, A ;
Giovannini, M ;
Faist, J .
APPLIED PHYSICS LETTERS, 2005, 86 (04) :041109-1
[3]   The sensitive detection of NO by Faraday modulation spectroscopy with a quantum cascade laser [J].
Ganser, H ;
Urban, W ;
Brown, AM .
MOLECULAR PHYSICS, 2003, 101 (4-5) :545-550
[4]   Cavity ringdown spectroscopic detection of nitric oxide with a continuous-wave quantum-cascade laser [J].
Kosterev, AA ;
Malinovsky, AL ;
Tittel, FK ;
Gmachl, C ;
Capasso, F ;
Sivco, DL ;
Baillargeon, JN ;
Hutchinson, AL ;
Cho, AY .
APPLIED OPTICS, 2001, 40 (30) :5522-5529
[5]  
Mansfield CD, 2002, CAN J ANAL SCI SPECT, V47, P14
[6]   Near-infrared diode laser spectroscopy in chemical process and environmental air monitoring [J].
Martin, PA .
CHEMICAL SOCIETY REVIEWS, 2002, 31 (04) :201-210
[7]   Spectroscopic detection of biological NO with a quantum cascade laser [J].
Menzel, L ;
Kosterev, AA ;
Curl, RF ;
Tittel, FK ;
Gmachl, C ;
Capasso, F ;
Sivco, DL ;
Baillargeon, JN ;
Hutchinson, AL ;
Cho, AY ;
Urban, W .
APPLIED PHYSICS B-LASERS AND OPTICS, 2001, 72 (07) :859-863
[8]   Laser photoacoustic detection allows in planta detection of nitric oxide in tobacco following challenge with avirulent and virulent Pseudomonas syringae pathovars [J].
Mur, LAJ ;
Santosa, IE ;
Laarhoven, LJJ ;
Holton, NJ ;
Harren, FJM ;
Smith, AR .
PLANT PHYSIOLOGY, 2005, 138 (03) :1247-1258
[9]   Sensitive absorption spectroscopy with a room-temperature distributed-feedback quantum-cascade laser [J].
Namjou, K ;
Cai, S ;
Whittaker, EA ;
Faist, J ;
Gmachl, C ;
Capasso, F ;
Sivco, DL ;
Cho, AY .
OPTICS LETTERS, 1998, 23 (03) :219-221
[10]   Sub-part-per-billion detection of nitric oxide in air using a thermoelectrically cooled mid-infrared quantum cascade laser spectrometer [J].
Nelson, DD ;
Shorter, JH ;
McManus, JB ;
Zahniser, MS .
APPLIED PHYSICS B-LASERS AND OPTICS, 2002, 75 (2-3) :343-350