Effect of Preparation Methods on the Performance of Pt/CeO2 Catalysts for the Catalytic Oxidation of Carbon Monoxide

被引:27
作者
Hong, Xiaowei [1 ]
Sun, Ye [1 ]
机构
[1] Beihang Univ, Sch Space & Environm, Beijing 100191, Peoples R China
关键词
CO; Pt/CeO2; Preparation method; TEMPERATURE CO OXIDATION; ROOM-TEMPERATURE; NANOPARTICLES; MECHANISM; SURFACE; CEO2; FORMALDEHYDE; COOXIDATION; ADSORPTION;
D O I
10.1007/s10562-016-1828-0
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A series of Pt/CeO2 catalysts were prepared by impregnation (IM), deposition-precipitation (DP) and impregnation-reduction (IR) methods, and their catalytic activities for the oxidation of CO were evaluated at room temperature. Pt/CeO2 (IR) catalyst presented the best catalytic activity, over which CO could be completely oxidized at room temperature. Based on the characterization, it was found that on Pt/CeO2 (IR) catalyst more negatively charged metallic Pt species existed, which could efficiently absorb atmospheric oxygen and thus enhance the CO oxidation. [GRAPHICS] .
引用
收藏
页码:2001 / 2008
页数:8
相关论文
共 35 条
[1]   Effects of reduction temperature and metal-support interactions on the catalytic activity Pt/γ-Al2O3 and Pt/TiO2 for the oxidation of CO in the presence and absence of H2 [J].
Alexeev, OS ;
Chin, SY ;
Engelhard, MH ;
Ortiz-Soto, L ;
Amiridis, MD .
JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (49) :23430-23443
[2]   Promoting effect of CeO2 in combustion synthesized Pt/CeO2 catalyst for CO oxidation [J].
Bera, P ;
Gayen, A ;
Hegde, MS ;
Lalla, NP ;
Spadaro, L ;
Frusteri, F ;
Arena, F .
JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (25) :6122-6130
[3]   On the role of redox properties of CuO/CeO2 catalysts in the preferential oxidation of CO in H2-rich gases [J].
Caputo, Tiziana ;
Lisi, Luciana ;
Pirone, Raffaele ;
Russo, Gennaro .
APPLIED CATALYSIS A-GENERAL, 2008, 348 (01) :42-53
[4]   Nanocrystalline CeO2 increases the activity of an for CO oxidation by two orders of magnitude [J].
Carrettin, S ;
Concepción, P ;
Corma, A ;
Nieto, JML ;
Puntes, VF .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (19) :2538-2540
[5]   Detailed surface reaction mechanism in a three-way catalyst [J].
Chatterjee, D ;
Deutschmann, O ;
Warnatz, J .
FARADAY DISCUSSIONS, 2001, 119 :371-384
[6]   Catalytic removal of formaldehyde at room temperature over supported gold catalysts [J].
Chen, Bing-Bing ;
Shi, Chuan ;
Crocker, Mark ;
Wang, Yu ;
Zhu, Ai-Min .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2013, 132 :245-255
[7]   The mechanism of low-temperature CO oxidation with Au/Fe2O3 catalysts:: a combined Mossbauer, FT-IR, and TAP reactor study [J].
Daniells, ST ;
Overweg, AR ;
Makkee, M ;
Moulijn, JA .
JOURNAL OF CATALYSIS, 2005, 230 (01) :52-65
[8]   Moisture effect on CO oxidation over Au/TiO2 catalyst [J].
Daté, M ;
Haruta, M .
JOURNAL OF CATALYSIS, 2001, 201 (02) :221-224
[9]   Au/Ce1-xZrxO2 as effective catalysts for low-temperature CO oxidation [J].
Dobrosz-Gomez, Izabela ;
Kocemba, Ireneusz ;
Rynkowski, Jacek M. .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2008, 83 (3-4) :240-255
[10]   MOLECULAR-BEAM INVESTIGATION OF HE, CO, AND O-2 SCATTERING FROM D(111) [J].
ENGEL, T .
JOURNAL OF CHEMICAL PHYSICS, 1978, 69 (01) :373-385