The epoxidized linseed oil as a secondary plasticizer inPVCprocessing

被引:2
|
作者
Thuy, Nguyen Thi [1 ]
Duc, Vu Minh [1 ]
机构
[1] Hanoi Univ Sci & Technol, Ctr Polymer Composite & Paper Technol, 1 Dai Co Viet, Hanoi 10000, Vietnam
关键词
PVC; epoxidized vegetable oil; epoxidized linseed oil; green plasticizer; ADDITIVES; EXPOSURE; PVC;
D O I
10.1002/vjch.202000023
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
By replacing the 10 php (parts per hundred polyvinylchloride) DOP plasticizer with the epoxidized linseed oil (ELO) in polyvinylchloride (PVC) processing, a slight increase in tensile properties was observed. The water, 30 wt.% acetic acid, 10 wt.% KOH solution, sunflower oil andn-hexane were used as media to evaluate the leaching characteristic. The sample weight increased slightly after soaking in water, 30 wt.% acetic solution and decreased slightly in 10 wt.% KOH solution, reduced sharply and strongly in sunflower oil andn-hexane. The presence of ELO has shown an improvement in migration, volatilization characteristics and thermal property of PVC. The positive effect of ELO as a secondary plasticizer was most evident after 72 hours of soaking inn-hexane because the shore A hardness of ELO plasticized PVC sample increased by 12 % while PVC sample without ELO was blistered and its shore A hardness could not be measured. The scanning electron microscopy was used to study the morphology of fractured surface the samples after immersing inn-hexane.
引用
收藏
页码:534 / 539
页数:6
相关论文
共 50 条
  • [1] MODIFIED EPOXIDIZED LINSEED OIL AS A PLASTICIZER-ANTIOXIDANT IN NR
    ABDELBARY, EM
    BADRAN, BM
    KHALIFA, WM
    YEHIA, AA
    ELASTOMERICS, 1978, 110 (11): : 38 - 42
  • [2] Effect of the epoxidized linseed oil concentration as natural plasticizer in vinyl plastisols
    O. Fenollar
    D. Garcia-Sanoguera
    L. Sanchez-Nacher
    J. Lopez
    R. Balart
    Journal of Materials Science, 2010, 45 : 4406 - 4413
  • [3] MODIFIED EPOXIDIZED LINSEED OIL AS A PLASTICIZER-ANTIOXIDANT IN NR.
    Abdel-Bary, E.M.
    Badran, B.M.
    Khalifa, W.M.
    Yehia, A.A.
    1978, 110 (11): : 38 - 42
  • [4] Effect of the epoxidized linseed oil concentration as natural plasticizer in vinyl plastisols
    Fenollar, O.
    Garcia-Sanoguera, D.
    Sanchez-Nacher, L.
    Lopez, J.
    Balart, R.
    JOURNAL OF MATERIALS SCIENCE, 2010, 45 (16) : 4406 - 4413
  • [5] Characterization of the curing process of vinyl plastisols with epoxidized linseed oil as a natural-based plasticizer
    Fenollar, O.
    Garcia-Sanoguera, D.
    Sanchez-Nacher, L.
    Lopez, J.
    Balart, R.
    JOURNAL OF APPLIED POLYMER SCIENCE, 2012, 124 (03) : 2550 - 2557
  • [6] Mechanical and morphological characterization of novel vinyl plastisols with epoxidized linseed oil as natural-based plasticizer
    Fenollar, O.
    Balart, R.
    Sanchez-Nacher, L.
    Garcia-Sanoguera, D.
    Boronat, T.
    5TH INTERNATIONAL CONFERENCE ON TIMES OF POLYMERS TOP AND COMPOSITES, 2010, 1255 : 326 - 328
  • [7] The Epoxidized Vietnam Rubber Seed Oil as a Secondary Plasticizer/Thermal Stabilizer in PVC Processing
    Thuy, Nguyen Thi
    Duc, Vu Minh
    Liem, Nguyen Thanh
    INTERNATIONAL JOURNAL OF POLYMER SCIENCE, 2021, 2021
  • [8] Synthesis and photopolymerization of norbornyl epoxidized linseed oil
    Chen, JX
    Soucek, MD
    Simonsick, WJ
    Celikay, RW
    POLYMER, 2002, 43 (20) : 5379 - 5389
  • [9] Epoxidized linseed oil as a plasticizer for All-Cellulose Composites based on cellulose acetate butyrate and micronized pulp fibers
    Valente, Bruno F. A.
    Karamysheva, Anna
    Silvestre, Armando J. D.
    Neto, Carlos Pascoal
    Vilela, Carla
    Freire, Carmen S. R.
    INDUSTRIAL CROPS AND PRODUCTS, 2023, 202
  • [10] ACRYLIC ACID DERIVATIVES OF PARTIALLY EPOXIDIZED LINSEED OIL
    RHEINECK, AE
    LAKSHMAN.PR
    JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1965, 42 (08) : A452 - &