Radiation-induced polymerization of styrene in highly concentrated emulsions

被引：0

作者：

Lukhovitskii, VI ^{[1
]}

Karpo, AI ^{[1
]}

Polikarpov, VV ^{[1
]}

Duflot, VR ^{[1
]}

Korneev, YN ^{[1
]}

Uzyumnikov, AL ^{[1
]}

机构：

[1] State Res Ctr Russina Federat, Obninsk Branch, Karpov Inst Phys Chem, Obninsk 249020, Kaluzhskaya Obl, Russia

来源：

VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A & SERIYA B | 1999年 / 41卷 / 04期

关键词：

D O I：

暂无

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

For radiation-induced polymerization of styrene in highly concentrated (gel-like) emulsions, the effect of the initiation rate on the kinetics of polymerization and the molecular mass of the resulting polymer was studied. It was found that the rate of initiation (irradiation intensity) does not affect the rate of polymerization, the number of latex particles, and the duration of the first stage. The molecular mass of polystyrene varies in inverse;proportion to the radiation intensity, and its molecular mass distribution corresponds to the Flory distribution.

引用

页码：600 / 608

页数：9

共 50 条

[41] RADIATION-INDUCED IONIC POLYMERIZATION [J].

METZ, DJ .

ADVANCES IN CHEMISTRY SERIES, 1969, (91) :202-&

[42] RADIATION-INDUCED POLYMERIZATION OF TETRAFLUOROETHYLENE [J].

TABATA, Y ;

ITO, W ;

OSHIMA, K .

JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY, 1970, A 4 (04) :789-&

[43] RADIATION-INDUCED POLYMERIZATION OF NITROETHYLENE [J].

YAMAOKA, H ;

WILLIAMS, F ;

HAYASHI, K .

TRANSACTIONS OF THE FARADAY SOCIETY, 1967, 63 (530P) :376-&

[44] RADIATION-INDUCED POLYMERIZATION OF PERFLUOROBUTADIENE [J].

TOY, MS ;

DIBARI, JC .

ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1972, :65-&

[45] RADIATION-INDUCED CATIONIC POLYMERIZATION [J].

STANNETT, VT .

ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1985, 189 (APR-) :9-POLY

[46] RADIATION-INDUCED POLYMERIZATION OF OCTAMETHYLCYCLOTETRASILOXANE [J].

TABATA, Y ;

SOBUE, H ;

KIMURA, H .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER LETTERS, 1964, 2 (1PB) :23-&

[47] RADIATION-INDUCED EMULSION POLYMERIZATION [J].

STANNETT, VT ;

STAHEL, EP .

ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1990, 200 :322-POLY

[48] RADIATION-INDUCED COPOLYMERIZATION OF ACRYLONITRILE WITH STYRENE [J].

TABATA, Y ;

HASHIZUME, Y ;

SOBUE, H .

JOURNAL OF POLYMER SCIENCE PART A-GENERAL PAPERS, 1964, 2 (8PA) :3649-&

[49] RADIATION-INDUCED COPOLYMERIZATION OF FORMALDEHYDE AND STYRENE [J].

CASTILLE, YP ;

STANNETT, V .

JOURNAL OF POLYMER SCIENCE PART A-1-POLYMER CHEMISTRY, 1966, 4 (9PA1) :2063-&

[50] Verification of controlled grafting of styrene from cellulose via radiation-induced RAFT polymerization [J].

Barsbay, Murat ;

Guven, Olgun ;

Stenzel, Martina H. ;

Davis, Thomas P. ;

Barner-Kowollik, Christopher ;

Barner, Leonie .

MACROMOLECULES, 2007, 40 (20) :7140-7147

← 1 2 3 4 5 →