Radiation-induced polymerization of styrene in highly concentrated emulsions

被引：0
|
作者：
Lukhovitskii, VI [1 ]
Karpo, AI [1 ]
Polikarpov, VV [1 ]
Duflot, VR [1 ]
Korneev, YN [1 ]
Uzyumnikov, AL [1 ]
机构：
[1] State Res Ctr Russina Federat, Obninsk Branch, Karpov Inst Phys Chem, Obninsk 249020, Kaluzhskaya Obl, Russia
来源：
VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A & SERIYA B | 1999年 / 41卷 / 04期
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中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
For radiation-induced polymerization of styrene in highly concentrated (gel-like) emulsions, the effect of the initiation rate on the kinetics of polymerization and the molecular mass of the resulting polymer was studied. It was found that the rate of initiation (irradiation intensity) does not affect the rate of polymerization, the number of latex particles, and the duration of the first stage. The molecular mass of polystyrene varies in inverse;proportion to the radiation intensity, and its molecular mass distribution corresponds to the Flory distribution.
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页码：600 / 608
页数：9
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