Janus carbosilane/phosphorhydrazone dendrimers synthesized by the 'click' Staudinger reaction

被引：14

作者：

Gottis, Sebastien ^{[1
,2
]}

Rodriguez, Lara-Isabel ^{[3
]}

Laurent, Regis ^{[1
,2
]}

Angurell, Inmaculada ^{[3
]}

Seco, Miquel ^{[3
]}

Rossell, Oriol ^{[3
]}

Majoral, Jean-Pierre ^{[1
,2
]}

Caminade, Anne-Marie ^{[1
,2
]}

机构：

[1] CNRS, LCC, F-31077 Toulouse 4, France

[2] Univ Toulouse, UPS, INPT, F-31077 Toulouse 4, France

[3] Univ Barcelona, Dept Quim Inorgan, E-08028 Barcelona, Spain

来源：

TETRAHEDRON LETTERS | 2013年 / 54卷 / 50期

关键词：

Dendrimer; Carbosilane dendron; Phosphorhydrazone dendron; Click reaction; Staudinger reaction; PHOSPHORUS-CONTAINING DENDRIMERS; FUNCTIONALIZATION; COMPLEXES; CHEMISTRY; PHOSPHINE; STRATEGY; ROUTE; CORE;

D O I：

10.1016/j.tetlet.2013.10.024

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first association of carbosilane dendrons (having a phosphine at the focal point) with phosphorhydrazone dendrons (having a thiophosphoryl azide at the focal point) has been successfully carried out by 'Staudinger click' reaction. The corresponding Janus dendrimers possess the characteristics of both components; they are oily as the carbosilane dendrons, and they can be easily functionalized as the phosphorhydrazone dendrons. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：6864 / 6867

页数：4

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