Research on the Thermodynamic Properties of the Room Temperature Ionic Liquid [BMIM][ClO3]

被引：0
作者：
Wang Xiao-Dan [1 ]
Han Chun [1 ]
Fan Hong-Tao [1 ]
机构：
[1] Shenyang Univ Chem Technol, Coll Appl Chem, Shenyang 110142, Peoples R China
来源：
JOURNAL OF SOLUTION CHEMISTRY | 2015年 / 44卷 / 09期
关键词：
Room temperature ionic liquid; BMIM][ClO3; Thermodynamic properties; Glasser's theory; Interstitial model; SURFACE-TENSION; PHYSICOCHEMICAL PROPERTIES; AIR; PRESSURE; SOLVENTS; DENSITY; METAL;
D O I：
10.1007/s10953-015-0380-7
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In the temperature range of 293.15-353.15 K, the densities and the surface tensions for a new room temperature ionic liquid (IL) [BMIM][ClO3] (1-butyl-3-methylimidazolium chlorate) were measured under a nitrogen atmosphere. In terms of Glasser's theory and the interstitial model, the thermodynamic properties of the IL are discussed and the standard molar entropy as well as the lattice energy for [BMIM][ClO3] have been estimated. Furthermore, the thermal expansion coefficient, alpha = 7.10 x 10(-4) K-1, calculated by the interstitial model, is in good agreement with alpha (experimental) = 7.50 x 10(-4) K-1.
引用
收藏
页码：1858 / 1865
页数：8
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