Research on the Thermodynamic Properties of the Room Temperature Ionic Liquid [BMIM][ClO3]

被引：0
作者：
Wang Xiao-Dan [1 ]
Han Chun [1 ]
Fan Hong-Tao [1 ]
机构：
[1] Shenyang Univ Chem Technol, Coll Appl Chem, Shenyang 110142, Peoples R China
来源：
JOURNAL OF SOLUTION CHEMISTRY | 2015年 / 44卷 / 09期
关键词：
Room temperature ionic liquid; BMIM][ClO3; Thermodynamic properties; Glasser's theory; Interstitial model; SURFACE-TENSION; PHYSICOCHEMICAL PROPERTIES; AIR; PRESSURE; SOLVENTS; DENSITY; METAL;
D O I：
10.1007/s10953-015-0380-7
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In the temperature range of 293.15-353.15 K, the densities and the surface tensions for a new room temperature ionic liquid (IL) [BMIM][ClO3] (1-butyl-3-methylimidazolium chlorate) were measured under a nitrogen atmosphere. In terms of Glasser's theory and the interstitial model, the thermodynamic properties of the IL are discussed and the standard molar entropy as well as the lattice energy for [BMIM][ClO3] have been estimated. Furthermore, the thermal expansion coefficient, alpha = 7.10 x 10(-4) K-1, calculated by the interstitial model, is in good agreement with alpha (experimental) = 7.50 x 10(-4) K-1.
引用
收藏
页码：1858 / 1865
页数：8
相关论文
共 50 条
  • [31] Excess thermodynamic properties of binary mixtures of ionic liquid (1-butyl-3-methylimidazolium hexafluorophosphate) with alkoxyalkanols at several temperatures
    Pal, Amalendu
    Gaba, Rekha
    Singh, Tejwant
    Kumar, Arvind
    JOURNAL OF MOLECULAR LIQUIDS, 2010, 154 (01) : 41 - 46
  • [32] Study on thermodynamic properties of a new air and water stable ionic liquid based on metal rhenium
    Fang, Da-Wei
    Zang, Shu-Liang
    Guan, Wei
    Tong, Jing
    Yang, Jia-Zhen
    JOURNAL OF CHEMICAL THERMODYNAMICS, 2010, 42 (07) : 860 - 863
  • [33] TEMPERATURE DEPENDENCE OF THERMODYNAMIC PROPERTIES OF IONIC SOLIDS
    Sharma, S. K.
    INTERNATIONAL JOURNAL OF MODERN PHYSICS B, 2009, 23 (11): : 2503 - 2509
  • [34] Interfacial properties of the ionic liquid [bmim] [triflate] over a wide range of temperatures
    Rivera, Jose L.
    Molina-Rodriguez, Luis
    Ramos-Estrada, Mariana
    Navarro-Santos, Pedro
    Lima, Enrique
    RSC ADVANCES, 2018, 8 (18): : 10115 - 10123
  • [35] Studies on liquid/liquid extraction of copper ion with room temperature ionic liquid
    Wei, GT
    Chen, JC
    Yang, ZS
    JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 2003, 50 (06) : 1123 - 1130
  • [36] Thermophysical and spectroscopic studies of room temperature ionic liquid, 1-butyl-3-methylimidazolium hexafluorophosphate in Tritons
    Chaudhary, Ganga Ram
    Bansal, Shafila
    Mehta, S. K.
    Ahluwalia, A. S.
    JOURNAL OF CHEMICAL THERMODYNAMICS, 2012, 50 : 63 - 70
  • [37] Physicochemical properties of phenyltrifluoroborate-based room temperature ionic liquids
    Iwasaki, Kazuki
    Yoshii, Kazuki
    Tsuda, Tetsuya
    Kuwabata, Susumu
    JOURNAL OF MOLECULAR LIQUIDS, 2017, 246 : 236 - 243
  • [38] Effects of imidazolium room temperature ionic liquids on the fluorescent properties of norfloxacin
    Zou, Yujie
    Wang, Huili
    Wang, Wenwei
    Ma, Meiping
    Wang, Ping
    Wang, Chengjun
    Wang, Xuedong
    LUMINESCENCE, 2012, 27 (06) : 495 - 500
  • [39] Correlation between Dynamic Heterogeneity and Local Structure in a Room-Temperature Ionic Liquid: A Molecular Dynamics Study of [bmim][PF6]
    Sarangi, Soumya S.
    Zhao, Wei
    Mueller-Plathe, Florian
    Balasubramanian, Sundaram
    CHEMPHYSCHEM, 2010, 11 (09) : 2001 - 2010
  • [40] Thermodynamic Properties of Binary Mixtures of the Amino Acid Ionic Liquids [Bmim][Glu] or [Bmim][Gly] with Methanol at T=298.15 to 313.15 K
    Yu, Zhichao
    Gao, Haiyan
    Wang, Haijun
    Chen, Lianwei
    JOURNAL OF SOLUTION CHEMISTRY, 2012, 41 (01) : 173 - 186
12345