Research on the Thermodynamic Properties of the Room Temperature Ionic Liquid [BMIM][ClO3]

被引：0
作者：
Wang Xiao-Dan [1 ]
Han Chun [1 ]
Fan Hong-Tao [1 ]
机构：
[1] Shenyang Univ Chem Technol, Coll Appl Chem, Shenyang 110142, Peoples R China
来源：
JOURNAL OF SOLUTION CHEMISTRY | 2015年 / 44卷 / 09期
关键词：
Room temperature ionic liquid; BMIM][ClO3; Thermodynamic properties; Glasser's theory; Interstitial model; SURFACE-TENSION; PHYSICOCHEMICAL PROPERTIES; AIR; PRESSURE; SOLVENTS; DENSITY; METAL;
D O I：
10.1007/s10953-015-0380-7
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In the temperature range of 293.15-353.15 K, the densities and the surface tensions for a new room temperature ionic liquid (IL) [BMIM][ClO3] (1-butyl-3-methylimidazolium chlorate) were measured under a nitrogen atmosphere. In terms of Glasser's theory and the interstitial model, the thermodynamic properties of the IL are discussed and the standard molar entropy as well as the lattice energy for [BMIM][ClO3] have been estimated. Furthermore, the thermal expansion coefficient, alpha = 7.10 x 10(-4) K-1, calculated by the interstitial model, is in good agreement with alpha (experimental) = 7.50 x 10(-4) K-1.
引用
收藏
页码：1858 / 1865
页数：8
相关论文
共 50 条
  • [1] Research on the Thermodynamic Properties of the Room Temperature Ionic Liquid [BMIM][ClO3]
    Wang Xiao-Dan
    Han Chun
    Fan Hong-Tao
    Journal of Solution Chemistry, 2015, 44 : 1858 - 1865
  • [2] Ionic liquid [bmim][NO3], an efficient medium for green and one-pot synthesis of benzothiazinones at room-temperature
    Sharifi, A.
    Abaee, M. S.
    Rouzgard, M.
    Mirzaei, M.
    SCIENTIA IRANICA, 2013, 20 (03) : 555 - 560
  • [3] Properties of ionic liquid BMIInCl4 of rare metal at room temperature
    Yang, JZ
    Zhang, QG
    Huang, M
    Xue, F
    Zang, SL
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2005, 26 (10): : 1873 - 1876
  • [4] Thermodynamic investigation of room temperature ionic liquid -: Heat capacity and thermodynamic functions of BPBF4
    Zhang, Z. H.
    Sun, L. X.
    Tan, Z. C.
    Xu, F.
    Lv, X. C.
    Zeng, J. L.
    Sawada, Y.
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2007, 89 (01) : 289 - 294
  • [5] Thermodynamic investigation of room temperature ionic liquid -: Heat capacity and thermodynamic functions of BMIBF4
    Zhang, Z. H.
    Tan, Z. C.
    Li, Y. S.
    Sun, L. X.
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2006, 85 (03) : 551 - 557
  • [6] Thermodynamic investigation of room temperature ionic liquid - The heat capacity and thermodynamic functions of BMIPF6
    Zhang, Z. H.
    Cui, T.
    Zhang, J. L.
    Xiong, H.
    Li, G. P.
    Sun, L. X.
    Xu, F.
    Cao, Z.
    Li, F.
    Zhao, J. J.
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2010, 101 (03) : 1143 - 1148
  • [7] Effect of temperature on the viscosities and the volumetric properties of the binary mixtures of the ionic liquids [bmim][PF6] and [bmim][CF3SO3]
    Paez, Manuel S.
    Vega, Yair A.
    Romero, Carmen M.
    JOURNAL OF MOLECULAR LIQUIDS, 2017, 243 : 78 - 84
  • [8] The physical properties of aqueous solutions of the ionic liquid [BMIM][BF4]
    Liu, Weiwei
    Zhao, Tianyu
    Zhang, Yumei
    Wang, Huaping
    Yu, Mingfang
    JOURNAL OF SOLUTION CHEMISTRY, 2006, 35 (10) : 1337 - 1346
  • [9] Properties of room temperature ionic liquid—3-ethyl-1-methylimidazolium ethyl sulfate
    Gui Jin-song
    Russian Journal of Physical Chemistry A, 2010, 84 : 760 - 765
  • [10] Properties of room temperature ionic liquid-3-ethyl-1-methylimidazolium ethyl sulfate
    Gui Jin-song
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2010, 84 (05) : 760 - 765
12345