Part I. The microstructural evolution in Ti-Al-NbO plus Bcc orthorhombic alloys

被引:295
作者
Boehlert, CJ [1 ]
Majumdar, BS
Seetharaman, V
Miracle, DB
机构
[1] Johns Hopkins Univ, Dept Mech Engn, Baltimore, MD 21218 USA
[2] Universal Energy Syst Inc, Dayton, OH 45432 USA
[3] USAF, Wright Patterson AFB, OH 45433 USA
来源
METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE | 1999年 / 30卷 / 09期
关键词
D O I
10.1007/s11661-999-0240-4
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Phase transformations and the resulting microstructural evolution of near-Ti2AlNb and Ti-12Al-38Nb O + bcc orthorhombic alloys were investigated. For the near-Ti2AlNb alloys, the processing temperatures were below the bcc transus, while, for Ti-12Al-38Nb, the processing temperature was supertransus. Phase evolution studies showed that these alloys contain several constituent phases, namely, bcc, O, and alpha(2); when present, the latter was in small quantities compared to the other phases. The transmission electron microscopy (TEM), scanning electron microscopy (SEM), and Xray investigations of samples that were solutionized and water quenched were used to estimate the phase fields, and a pseudobinary diagram based on Ti = 50 at. pct was modified. The aging transformation behavior was studied in detail. For solutionizing temperatures between 875 degrees C and the bcc transus, the phase composition and volume fraction of the near-Ti2AlNb alloys adjusted through relative size changes of the equiaxed B2, O, and alpha(2) grains. The aging behavior followed three distinct transformation modes, dependent on the solutionizing and aging temperatures. Widmanstatten formation was observed when a new phase evolved from a parent phase. Thus, Widmanstatten O phase precipitated within the B2 phase for supertransus fully B2 microstructures, as well as for subtransus alpha(2) + B2 microstructures. Similarly, Widmanstatten B2 phase can form from a fully O microstructure, a transformation that has not been observed before. In the case of equiaxed O + B2 solutionized and water-quenched microstructures, Widmanstatten O-phase formation occurred only below 875 degrees C. For the subtransus-solutionized and water-quenched microstructures, a second aging transformation mode, cellular precipitation, was dominant below 750 degrees C. This involved formation of coarse and lenticular O phase that grew into the prior B2 grains from the grain boundaries. A third transformation mode involved composition-invariant transformation, where the fully B2 supertransus-solutionized and water-quenched microstructure transformed to a fully O microstructure at 650 degrees C. This microstructure reprecipitated B2 phase out of the O phase with continued aging time. For Ti-12Al-38Nb, Widmanstatten O precipitation remained the only transformation mode. It is shown that subtransus processing offers flexibility in controlling microstructures through postprocessing heat treatments.
引用
收藏
页码:2305 / 2323
页数:19
相关论文
共 39 条
[1]  
[Anonymous], 1973, TITANIUM SCI TECHNOL
[2]  
[Anonymous], TITANIUM 95
[3]   A NEW ORDERED ORTHORHOMBIC PHASE IN A TI3AL-NB ALLOY [J].
BANERJEE, D ;
GOGIA, AK ;
NANDI, TK ;
JOSHI, VA .
ACTA METALLURGICA, 1988, 36 (04) :871-882
[4]   The intermetallic Ti2AlNb [J].
Banerjee, D .
PROGRESS IN MATERIALS SCIENCE, 1997, 42 (1-4) :135-158
[5]   COHERENT PRECIPITATES IN THE BCC ORTHORHOMBIC 2-PHASE FIELD OF THE TI-AL-NB SYSTEM [J].
BENDERSKY, LA ;
BOETTINGER, WJ ;
ROYTBURD, A .
ACTA METALLURGICA ET MATERIALIA, 1991, 39 (08) :1959-1969
[6]  
Boehlert C.J., 1997, WLTR974118 AIR FORC
[7]   Role of matrix microstructure on: Room-temperature tensile properties and fiber-strength utilization of an orthorhombic Ti-alloy-based composite [J].
Boehlert, CJ ;
Majumdar, BS ;
Krishnpurthy, S ;
Miracle, DB .
METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 1997, 28 (02) :309-323
[8]   Part II. The creep behavior of Ti-Al-NbO plus Bcc orthorhombic alloys [J].
Boehlert, CJ ;
Miracle, DB .
METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 1999, 30 (09) :2349-2367
[9]  
BOEHLERT CJ, 1997, STRUCTURAL INTERMETA, P795
[10]   On the process of transition of the cubic-body-centered modification into the hexagonal-close-packed modification of zirconium [J].
Burgers, WG .
PHYSICA, 1934, 1 :561-586