Azaheteroalkene metathesis: Reaction of imines with molybdenum(vi) bis(imide) complexes

被引：37

作者：

Cantrell, GK ^{[1
]}

Meyer, TY ^{[1
]}

机构：

[1] UNIV PITTSBURGH,DEPT CHEM,PITTSBURGH,PA 15260

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 16期

关键词：

D O I：

10.1039/a702780j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bis(imide) complexes (dme)Ci(2)Mo(=NR)(2)(R = Bu-t, C6H3Pr2i-2,6) and ((BuO)-O-t)(2)Mo(=NAr)(2) (Ar = C6H3Pr2i-2,6) undergo imide/imine metathesis with PhN=CH(Bu-t) or (Pr-n)N=CHPh.

引用

页码：1551 / 1552

页数：2

共 16 条

[11] INVESTIGATIONS OF POLYMERIZATIONS AND METATHESIS REACTIONS .9. METATHESIS OF CARBODIIMIDES WITH TUNGSTEN(VI)-IMIDO COMPLEXES [J].

MEISEL, I ;

HERTEL, G ;

WEISS, K .

JOURNAL OF MOLECULAR CATALYSIS, 1986, 36 (1-2) :159-162

[12] ZIRCONIUM-MEDIATED IMINE METATHESIS - SYNTHESIS OF 2,4-DIAZA-1-ZIRCONIACYCLOBUTANES AND THE MECHANISM OF THEIR REACTIONS WITH IMINES AND ALKYNES [J].

MEYER, KE ;

WALSH, PJ ;

BERGMAN, RG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (06) :2669-2670

[13] A MECHANISTIC STUDY OF THE CYCLOADDITION-CYCLOREVERSION REACTIONS OF THE ZIRCONIUM IMIDO COMPLEX CP(2)ZR(N-T-BU)(THF) WITH ORGANIC IMINES AND AZIDES [J].

MEYER, KE ;

WALSH, PJ ;

BERGMAN, RG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (03) :974-985

[14]

Nugent W.A., 1988, METAL LIGAND MULTIPL

[15] LIVING RING-OPENING METATHESIS POLYMERIZATION CATALYZED BY WELL-CHARACTERIZED TRANSITION-METAL ALKYLIDENE COMPLEXES [J].

SCHROCK, RR .

ACCOUNTS OF CHEMICAL RESEARCH, 1990, 23 (05) :158-165

[16] ORGANOIMIDO COMPLEXES OF THE TRANSITION-METALS [J].

WIGLEY, DE .

PROGRESS IN INORGANIC CHEMISTRY, VOL 42, 1994, 42 :239-482

← 1 2 →