Azaheteroalkene metathesis: Reaction of imines with molybdenum(vi) bis(imide) complexes

被引：37

作者：

Cantrell, GK ^{[1
]}

Meyer, TY ^{[1
]}

机构：

[1] UNIV PITTSBURGH,DEPT CHEM,PITTSBURGH,PA 15260

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 16期

关键词：

D O I：

10.1039/a702780j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bis(imide) complexes (dme)Ci(2)Mo(=NR)(2)(R = Bu-t, C6H3Pr2i-2,6) and ((BuO)-O-t)(2)Mo(=NAr)(2) (Ar = C6H3Pr2i-2,6) undergo imide/imine metathesis with PhN=CH(Bu-t) or (Pr-n)N=CHPh.

引用

页码：1551 / 1552

页数：2

共 16 条

[11] INVESTIGATIONS OF POLYMERIZATIONS AND METATHESIS REACTIONS .9. METATHESIS OF CARBODIIMIDES WITH TUNGSTEN(VI)-IMIDO COMPLEXES[J]. MEISEL, I;HERTEL, G;WEISS, K. JOURNAL OF MOLECULAR CATALYSIS, 1986(1-2)
[12] ZIRCONIUM-MEDIATED IMINE METATHESIS - SYNTHESIS OF 2,4-DIAZA-1-ZIRCONIACYCLOBUTANES AND THE MECHANISM OF THEIR REACTIONS WITH IMINES AND ALKYNES[J]. MEYER, KE;WALSH, PJ;BERGMAN, RG. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994(06)
[13] A MECHANISTIC STUDY OF THE CYCLOADDITION-CYCLOREVERSION REACTIONS OF THE ZIRCONIUM IMIDO COMPLEX CP(2)ZR(N-T-BU)(THF) WITH ORGANIC IMINES AND AZIDES[J]. MEYER, KE;WALSH, PJ;BERGMAN, RG. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995(03)
[14] Nugent W.A., 1988, METAL LIGAND MULTIPL
[15] LIVING RING-OPENING METATHESIS POLYMERIZATION CATALYZED BY WELL-CHARACTERIZED TRANSITION-METAL ALKYLIDENE COMPLEXES[J]. SCHROCK, RR. ACCOUNTS OF CHEMICAL RESEARCH, 1990(05)
[16] ORGANOIMIDO COMPLEXES OF THE TRANSITION-METALS[J]. WIGLEY, DE. PROGRESS IN INORGANIC CHEMISTRY, VOL 42, 1994

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