Characteristics of the La0.6Sr0.4Fe0.8Co0.2O3-δ electrode in contact with the lanthanum gallate-based electrolyte

被引:1
作者
Nikonov, A. V. [1 ]
Shkerin, S. N. [2 ]
Lipilin, A. S. [1 ]
Gyrdasova, O. I. [3 ]
Stepanov, D. M. [1 ]
机构
[1] Russian Acad Sci, Inst Electrophys, Ural Branch, Ekaterinburg, Russia
[2] Russian Acad Sci, Inst High Temp Electrochem, Ural Branch, Ekaterinburg, Russia
[3] Russian Acad Sci, Inst Solid State Chem, Ural Branch, Ekaterinburg, Russia
基金
俄罗斯基础研究基金会;
关键词
lanthanum-gallate electrolyte; strontium lanthanum ferro-cobaltite; polarization resistance; OXIDE FUEL-CELLS; REACTION-MECHANISMS; REDUCTION; TRANSPORT; CATHODES;
D O I
10.1134/S1023193513080156
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Lowering the working temperature of solid oxide fuel cells (SOFCs) is the main trend in their development, which requires selection of materials for electrolyte and electrodes. A highly conducting lanthanum gallate-based electrolyte is a promising material for creating medium-temperature SOFCs. The electrochemical characteristics of the La0.6Sr0.4Fe0.8Co0.2O3 - delta cathode that contacted with the La0.88Sr0.12Ga0.82Mg0.18O2.85 electrolyte subject to electrode formation temperatures have been investigated. It was found that at optimum bake-on temperatures of 1200-1250A degrees C, the cathode polarization resistance at 800A degrees C was similar to 0.08 Ohm cm(2), which is comparable to the world's best achievements.
引用
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页码:813 / 816
页数:4
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