Fast, microwave-assisted synthesis of monodisperse HfO2 nanoparticles

被引：43

作者：

De Roo, Jonathan ^{[1
,2
]}

De Keukeleere, Katrien ^{[1
]}

Feys, Jonas ^{[1
]}

Lommens, Petra ^{[1
]}

Hens, Zeger ^{[2
,3
]}

Van Driessche, Isabel ^{[1
]}

机构：

[1] Univ Ghent, Sol Gel Ctr Res Inorgan Powders & Thin Films Synt, B-9000 Ghent, Belgium

[2] Univ Ghent, B-9000 Ghent, Belgium

[3] Univ Ghent, Ctr Nano & Biophoton NB Photon, B-9000 Ghent, Belgium

来源：

JOURNAL OF NANOPARTICLE RESEARCH | 2013年 / 15卷 / 07期

关键词：

Benzyl alcohol; Microwave; Ligand exchange; Hafnium oxide; NONAQUEOUS SYNTHESIS; OXIDE; ZRO2; FILMS;

D O I：

10.1007/s11051-013-1778-z

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A conventional solvothermal synthesis was compared to a microwave-assisted method for the synthesis of HfO2 nanoparticles. In a microwave, the reaction could be completed in 3 h, compared to 3 days in an autoclave. In the microwave synthesis, the ensemble of particles was found to have a better size dispersion and a smaller average size (4 nm). The reaction mechanism was investigated and proof for an ether elimination process was provided. Post-synthetic modification with dopamine or dodecanoic acid permitted the suspension of the synthesized particles in both polar and apolar solvents, which is an advantage for further processing.

引用

页数：11

共 42 条

[1] Characterization of hafnium oxide thin films prepared by electron beam evaporation [J].

Al-Kuhaili, MF ;

Durrani, SMA ;

Khawaja, EE .

JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2004, 37 (08) :1254-1261

[2] Microwave-Assisted Synthesis of Colloidal Inorganic Nanocrystals [J].

Baghbanzadeh, Mostafa ;

Carbone, Luigi ;

Cozzoli, P. Davide ;

Kappe, C. Oliver .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (48) :11312-11359

[3] One-minute synthesis of crystalline binary and ternary metal oxide nanoparticles [J].

Bilecka, Idalia ;

Djerdj, Igor ;

Niederberger, Markus .

CHEMICAL COMMUNICATIONS, 2008, (07) :886-888

[4] Microwave-Assisted Nonaqueous Sol-Gel Chemistry for Highly Concentrated ZnO-Based Magnetic Semiconductor Nanocrystals [J].

Bilecka, Idalia ;

Luo, Li ;

Djerdj, Igor ;

Rossell, Marta D. ;

Jagodic, Marko ;

Jaglicic, Zvonko ;

Masubuchi, Yuji ;

Kikkawa, Shinichi ;

Niederberger, Markus .

JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (05) :1484-1495

[5] Synthesis and Structural Characterization of a Family of Modified Hafnium tert-Butoxide for Use as Precursors to Hafnia Nanoparticles [J].

Boyle, Timothy J. ;

Steele, Leigh Anna M. ;

Burton, Patrick D. ;

Hoppe, Sarah M. ;

Lockhart, Chelsea ;

Rodriguez, Mark A. .

INORGANIC CHEMISTRY, 2012, 51 (22) :12075-12092

[6] Solvothermal and surfactant-free synthesis of crystalline Nb2O5, Ta2O5, HfO2, and Co-doped HfO2 nanoparticles [J].

Buha, Jelena ;

Arcon, Denis ;

Niederberger, Markus ;

Djerdj, Igor .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2010, 12 (47) :15537-15543

[7] Microstructural and thermal investigations of HfO2 nanoparticles [J].

Chaubey, Girija S. ;

Yao, Yuan ;

Makongo, Julien P. A. ;

Sahoo, Pranati ;

Misra, Dinesh ;

Poudeu, Pierre F. P. ;

Wiley, John B. .

RSC ADVANCES, 2012, 2 (24) :9207-9213

[8] REACTIVE EVAPORATION OF LOW-DEFECT DENSITY HAFNIA [J].

CHOW, R ;

FALABELLA, S ;

LOOMIS, GE ;

RAINER, F ;

STOLZ, CJ ;

KOZLOWSKI, MR .

APPLIED OPTICS, 1993, 32 (28) :5567-5574

[9] Beneficial Effects of Microwave-Assisted Heating versus Conventional Heating in Noble Metal Nanoparticle Synthesis [J].

Dahal, Naween ;

Garcia, Stephany ;

Zhou, Jiping ;

Humphrey, Simon M. .

ACS NANO, 2012, 6 (11) :9433-9446

[10] Synthesis of Hafnium Oxide-Gold Core-Shell Nanoparticles [J].

Dahal, Naween ;

Chikan, Viktor .

INORGANIC CHEMISTRY, 2012, 51 (01) :518-522

← 1 2 3 4 5 →