Effective synthesis to control the growth of polyaniline nanofibers by interfacial polymerization

被引:33
作者
Li, Ruiqi [1 ,2 ]
Chen, Zheng [1 ]
Li, Junqing [1 ]
Zhang, Chunhong [1 ]
Guo, Qing [1 ]
机构
[1] Harbin Engn Univ, Coll Mat Sci & Chem Engn, Key Lab Superlight Mat & Surface Technol, Harbin 150001, Peoples R China
[2] Harbin Inst Technol, State Key Lab Adv Welding & Joining, Harbin 150001, Peoples R China
基金
中国国家自然科学基金;
关键词
Polyaniline; Nanofiber; Interfacial Polymerization; Morphology; NANOTUBES;
D O I
10.1016/j.synthmet.2013.02.020
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Polyaniline nanofibers with diameters under 100 nm were successfully synthesized by interfacial polymerization. The effect of synthesis conditions such as [An], [APS], solvent, and reaction temperature on the morphologies of polyaniline nanofibers was carefully investigated via scanning electron microscopy. The further characterization including FT-IR spectroscopy and electrical conductivity are presented. And the mechanism controlling the growth of polyaniline nanofibers was discussed in detail. Interfacial polymerization is shown to be effective to produce bulk quantities of nanofibers. (c) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:39 / 44
页数:6
相关论文
共 25 条
[11]   Polyaniline superstructures created by a templating effect of organogels [J].
Li, C ;
Hatano, T ;
Takeuchi, M ;
Shinkai, S .
CHEMICAL COMMUNICATIONS, 2004, (20) :2350-2351
[12]   Shape and aggregation control of nanoparticles: Not shaken, not stirred [J].
Department of Chemistry and Biochemistry, California NanoSystems Institute, University of California, Los Angeles, Los Angeles, CA 90095-1569, United States .
J. Am. Chem. Soc., 2006, 3 (968-975)
[13]   Synthesis of dendritic polyaniline nanofibers in a surfactant gel [J].
Li, GC ;
Zhang, ZK .
MACROMOLECULES, 2004, 37 (08) :2683-2685
[14]   Electrostatically-generated nanofibers of electronic polymers [J].
MacDiarmid, AG ;
Jones, WE ;
Norris, ID ;
Gao, J ;
Johnson, AT ;
Pinto, NJ ;
Hone, J ;
Han, B ;
Ko, FK ;
Okuzaki, H ;
Llaguno, M .
SYNTHETIC METALS, 2001, 119 (1-3) :27-30
[15]   Nobel Lecture: "Synthetic metals": A novel role for organic polymers [J].
MacDiarmid, AG .
REVIEWS OF MODERN PHYSICS, 2001, 73 (03) :701-712
[16]  
MEDHEKAR VN, 2002, J AM CHEM SOC, V4, P2300
[17]   Conducting polyaniline nanotubes by template-free polymerization [J].
Qiu, HJ ;
Wan, MX ;
Matthews, B ;
Dai, LM .
MACROMOLECULES, 2001, 34 (04) :675-677
[18]   On the origin of colloidal particles in the dispersion polymerization of aniline [J].
Stejskal, J ;
Sapurina, I .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2004, 274 (02) :489-495
[19]   Well-aligned polyaniline nano-fibril array membrane and its field emission property [J].
Wang, CW ;
Wang, Z ;
Li, MK ;
Li, HL .
CHEMICAL PHYSICS LETTERS, 2001, 341 (5-6) :431-434
[20]   Morphological control of self-assembly polyaniline micro/nano-structures using dichloroacetic acid [J].
Wang, Hongjuan ;
Lu, Yun .
SYNTHETIC METALS, 2012, 162 (15-16) :1369-1374