Poly [2-(cinnamoyloxy)ethyl methacrylate-co-octamethacryl-POSS] nanocomposites: Synthesis and properties

被引：11
作者：
Kumar, A. B. V. Kiran [1 ,2 ]
Thangadurai, T. Daniel [1 ,3 ]
Lee, Yong-Ill [1 ]
机构：
[1] Changwon Natl Univ, Dept Chem, Anastro Lab, Chang Won 641773, South Korea
[2] Kongju Natl Univ, Dept Chem, Kong Ju 314701, South Korea
[3] Sri Ramakrishna Inst, Coll Engn, Dept Nanotechnol, Coimbatore 136702, Tamil Nadu, India
来源：
REACTIVE & FUNCTIONAL POLYMERS | 2013年 / 73卷 / 09期
基金：
新加坡国家研究基金会;
关键词：
Nanocomposites; POSS; Copolymerization; Optical properties; Thermal properties; THERMAL-PROPERTIES; HYBRID; COPOLYMERS; MORPHOLOGY; INCREASE;
D O I：
10.1016/j.reactfunctpolym.2013.05.010
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Poly [2-(cinnamoyloxy)ethyl methacrylate-co-octamethacryl-POSS] nanocomposites were synthesized from octamethacryl-POSS and 2-(cinnamoyloxy)ethyl methacrylate (CEM) by free radical polymerization. The chemical structures and morphologies of these nanocomposites were determined by FTIR, Si-29 NMR, energy-dispersive spectroscopy (EDS), X-ray powder diffraction (XRD), and scanning electron microscopy (SEM) techniques. The XRD data showed that the materials were amorphous in nature, indicating that PUSS formed an aggregate instead of a crystalline form in the polymer matrix. The POSS-CEM nanocomposites exhibited high thermal stability. Excitation and emission of the CEM-incorporated POSS nanocomposites, studied in the solid state, exhibited blue emission with CIE (x, 0.178; y, 0.137) coordinates, in addition to an emission intensity that increased with increasing CEM (monomer) concentration. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1175 / 1179
页数：5
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