Synthesis of the Nowotny phase Mo4.8Si3C0.6 from Mo5Si3 + carbon mixtures

被引：6

作者：

Gnesin, B. A. ^{[1
]}

Gnesin, I. B. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Solid State Phys, Chernogolovka 142432, Moscow Oblast, Russia

来源：

INORGANIC MATERIALS | 2015年 / 51卷 / 10期

基金：

俄罗斯基础研究基金会;

关键词：

MECHANICAL-PROPERTIES; MO-LESS-THAN-OR-EQUAL-TO-5SI3C-LESS-THAN-OR-EQUAL-TO-1;

D O I：

10.1134/S0020168515090071

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A simple, efficient method for the synthesis of the Nowotny phase Mo4.8Si3C0.6 from mixtures of the Mo5Si3 silicide and carbon in the form of carbon black or diamond powder has been proposed. The synthesis of the Nowotny phase via reaction sintering has been shown to be more complete in samples prepared at reduced compaction pressures, which has been tentatively attributed to the considerable role of carbon transport through the gas phase. In samples quenched from the liquid state in a levitation melting system, the highest volume fraction of Mo4.8Si3C0.6 has been obtained using starting mixtures of Mo5Si3 and diamond powder.

引用

页码：991 / 998

页数：8

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