Effects of iron promoter on reactions of 1-butene adsorbed on sulfated zirconias

被引：10

作者：

Sikabwe, EC ^{[1
]}

White, RL ^{[1
]}

机构：

[1] UNIV OKLAHOMA,DEPT CHEM & BIOCHEM,NORMAN,OK 73019

来源：

CATALYSIS LETTERS | 1997年 / 44卷 / 3-4期

关键词：

sulfated zirconia; promoted sulfated zirconia; TEMPERATURE-PROGRAMMED DESORPTION; SOLID SUPERACID CATALYST; N-BUTANE ISOMERIZATION; INFRARED-SPECTROSCOPY; THERMAL-ANALYSIS; MANGANESE; H-ZSM-5; ACIDS;

D O I：

10.1023/A:1018966117719

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Volatile hydrocarbons evolved by heating sulfated zirconia and iron promoted sulfated zirconias containing adsorbed 1-butene are detected and characterized by using temperature-programmed desorption coupled with mass spectrometry and with capillary gas chromatography-mass spectrometry. The presence of iron promoter has a dramatic effect on both the temperature at which volatile products evolve from catalysts and the composition of volatile hydrocarbon mixtures. These differences reflect differences in the reactivities of surface carbenium ions. Reactions on unpromoted and iron promoted catalysts are consistent with an apparent decrease in the Lewis acidity of surface carbenium ions when iron promoter is present.

引用

页码：177 / 183

页数：7

共 27 条

[1] ISOMERIZATION OF C-13 LABELED BUTANE OVER FE,MN PROMOTED SULFATED ZRO2 CATALYST [J].