Synthesis, structure, and characterization of two 1-D homometallic coordination polymers based on carboxylate-functionlized salen ligands

被引:1
作者
Hao, Lina [1 ]
Lu, Ying [1 ]
He, Zhenzhen [1 ]
Lan, Qing [1 ]
Wang, Enbo [1 ]
机构
[1] NE Normal Univ, Dept Chem, Minist Educ, Key Lab Polyoxometalate Sci, Jilin, Peoples R China
基金
中国国家自然科学基金;
关键词
Salen ligand; Coordination polymer; One-step synthesis; Structure; Magnetic property; HYDROLYTIC KINETIC RESOLUTION; METAL-ORGANIC FRAMEWORKS; HUMAN ALPHA-THROMBIN; SCHIFF-BASE; MAGNETIC-PROPERTIES; COMPLEXES; CONSTRUCTION; INHIBITION; EPOXIDES; CATALYST;
D O I
10.1080/00958972.2015.1062093
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Two 1-D homometallic coordination polymers 1 and 2 have been prepared by one-step hydrothermal reactions of carboxylate-functionalized salen ligands with Co(II) and Mn(II), respectively. Single-crystal X-ray diffraction analyses reveal that both the 1-D chains give 3-D supramolecular structures through intermolecular hydrogen bonds and packing interactions. Magnetic investigation of 2 indicates the presence of antiferromagnetic interactions in 1-D chains.
引用
收藏
页码:2682 / 2690
页数:9
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