1,4-Oxazine

被引：7

作者：

Aitken, R. Alan ^{[1
]}

Aitken, Kati M. ^{[1
]}

Carruthers, Philip G. ^{[1
]}

Jean, Marc-Alexandre ^{[1
]}

Slawin, Alexandra M. Z. ^{[1
]}

机构：

[1] Univ St Andrews, EaStCHEM Sch Chem, St Andrews KY16 9ST, Fife, Scotland

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 97期

关键词：

BETA-LACTAMS; HOMALINE; SYSTEMS; ANALOGS; ACCESS;

D O I：

10.1039/c3cc47801g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The fundamental heterocyclic compound 1,4-oxazine has been generated using FVP. It is the first parent heterocycle among all the possible isomeric oxazines, thiazines and their heavier atom analogues to be characterised spectroscopically, and is shown to exist in solution entirely as the 4H-isomer. X-ray structure determination of the N-Boc precursor shows significant deviations from theoretically predicted geometric parameters.

引用

页码：11367 / 11369

页数：3

共 29 条

[1]

Aitken R.A., 2001, CHEM HETEROCYCL COMP, V37, P1526, DOI DOI 10.1023/A:1014561327169

[2]

Aitken R. A., 2008, COMPR HETEROCYCL CHE, V8, P461

[3] EFFECT OF RING STRAIN ON THE FORMATION AND PYROLYSIS OF SOME DIELS-ALDER ADDUCTS OF 2-SULFOLENE (2,3-DIHYDROTHIOPHENE 1,1-DIOXIDE) AND MALEIC-ANHYDRIDE WITH 1,3-DIENES AND PRODUCTS DERIVED THEREFROM [J].

AITKEN, RA ;

CADOGAN, JIG ;

GOSNEY, I .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1994, (08) :927-931

[4]

[Anonymous], 956939 CCDC

[5] THE PREPARATION OF 1,4-THIAZINE [J].

BARKENBUS, C ;

LANDIS, PS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1948, 70 (02) :684-685

[6]

BARTSCH H, 1979, MONATSH CHEM, V110, P267, DOI 10.1007/BF00911914

[7] Conformational flexibility of antiaromatic 1,4 heterocyclic analogues of 1,4-cyclohexadiene [J].

Borbulevych, OY ;

Shishkin, OV .

JOURNAL OF MOLECULAR STRUCTURE, 1998, 446 (1-2) :11-14

[8] Synthesis of 3-substituted and 2,3-disubstituted-4H-1,4-benzoxazines [J].

Buon, C ;

Chacun-Lefèvre, L ;

Rabot, R ;

Bouyssou, P ;

Coudert, G .

TETRAHEDRON, 2000, 56 (04) :605-614

[9] NEW BENZOXAZINE AND BENZOTHIAZINE DYES [J].

CHIOCCARA, F ;

PROTA, G ;

THOMSON, RH .

TETRAHEDRON, 1976, 32 (12) :1407-1409

[10] Easy access to new heterocyclic systems: 1,4-oxazine and substituted 1,4-oxazines [J].

Claveau, Elise ;

Gillaizeau, Isabelle ;

Blu, Jerome ;

Bruel, Amelie ;

Coudert, Gerard .

JOURNAL OF ORGANIC CHEMISTRY, 2007, 72 (13) :4832-4836

← 1 2 3 →