Flexibility of components alters the self-assembly pathway of Pd2L4 coordination cages

被引：19
|
作者：
Kai, Shumpei [1 ]
Maddala, Sai Prakash [2 ]
Kojima, Tatsuo [1 ]
Akagi, Shota [1 ]
Harano, Koji [2 ]
Nakamura, Eiichi [2 ]
Hiraoka, Shuichi [1 ]
机构：
[1] Univ Tokyo, Grad Sch Arts & Sci, Dept Basic Sci, Meguro Ku, 3-8-1 Komaba, Tokyo 1538902, Japan
[2] Univ Tokyo, Grad Sch Sci, Dept Chem, Bunkyo Ku, 7-3-1 Hongo, Tokyo 1130033, Japan
来源：
DALTON TRANSACTIONS | 2018年 / 47卷 / 10期
关键词：
SUBSTITUTION-REACTIONS; EFFICIENT; BINDING; LIGAND; CAPSULE; RECOGNITION; MULTICAVITY; COMPLEXES; CHEMISTRY; CATALYSIS;
D O I：
10.1039/c8dt00112j
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The self-assembly process of a Pd2L4 cage consisting of flexible ditopic ligands and Pd(II) ions was revealed by QASAP (quantitative analysis of self-assembly process), which enables one to obtain information about the intermediates transiently produced during the self-assembly as the average composition of all the intermediates. It was found that the dominant pathway to the cage is the formation of a submicrometre-sized sheet structure, which was characterized by dynamic light scattering (DLS) and scanning transmission electron microscopy (STEM), followed by the addition of free ditopic ligands to the Pd(II) centres of the sheet structure to trigger the cage formation. This assembly process is completely different from that of a Pd2L4 cage composed of rigid ditopic ligands, indicating that the flexibility of the components strongly affects the self-assembly process.
引用
收藏
页码：3258 / 3263
页数：6
相关论文
共 50 条
  • [21] Pathway selection in the self-assembly of Rh4L4 coordination squares under kinetic control
    Okazawa, Atsushi
    Sanada, Naoki
    Takahashi, Satoshi
    Sato, Hirofumi
    Hiraoka, Shuichi
    COMMUNICATIONS CHEMISTRY, 2023, 6 (01)
  • [22] Self-assembly processes of octahedron-shaped Pd6L12 cages
    Komine, Shohei
    Tateishi, Tomoki
    Kojima, Tatsuo
    Nakagawa, Haruna
    Hayashi, Yasuhiro
    Takahashi, Satoshi
    Hiraoka, Shuichi
    DALTON TRANSACTIONS, 2019, 48 (13) : 4139 - 4148
  • [23] Elucidating Anion-Dependent Formation and Conversion of Pd2L4 and Pd3L6 Metal-Organic Cages by Complementary Techniques
    Yu, Hui-Juan
    Liu, Zhi-Min
    Pan, Mei
    Wu, Kai
    Wei, Zhang-Wen
    Xu, Yao-Wei
    Fan, Ya-Nan
    Wang, Hai-Ping
    Su, Cheng-Yong
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2018, (01) : 80 - 85
  • [24] Entropy directs the self-assembly of supramolecular palladium coordination macrocycles and cages
    Poole, D. A., III
    Bobylev, E. O.
    Mathew, S.
    Reek, J. N. H.
    CHEMICAL SCIENCE, 2022, 13 (34) : 10141 - 10148
  • [25] Stimuli-responsive Pd2L4 metallosupramolecular cages: towards targeted cisplatin drug delivery
    Lewis, James E. M.
    Gavey, Emma L.
    Cameron, Scott A.
    Crowley, James D.
    CHEMICAL SCIENCE, 2012, 3 (03) : 778 - 784
  • [26] Cyclization or bridging: which occurs faster is the key to the self-assembly mechanism of Pd6L3 coordination prisms
    Zhang, Xinman
    Takahashi, Satoshi
    Aratsu, Keisuke
    Kikuchi, Isamu
    Sato, Hirofumi
    Hiraoka, Shuichi
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2022, 24 (05) : 2997 - 3006
  • [27] Self-Assembly and Host Guest Interactions of Pd3L2 Metallocryptophanes with Photoisomerizable Ligands
    Britton, Edward
    Ansell, Richard J.
    Howard, Mark J.
    Hardie, Michaele J.
    INORGANIC CHEMISTRY, 2021, 60 (17) : 12912 - 12923
  • [28] Exploiting Supramolecular Interactions to Control Isomer Distributions in Reduced-Symmetry [Pd2L4]4+ Cages
    Vasdev, Roan A. S.
    Preston, Dan
    Casey-Stevens, Caitlin A.
    Marti-Centelles, Vicente
    Lusby, Paul J.
    Garden, Anna L.
    Crowley, James D.
    INORGANIC CHEMISTRY, 2022, 62 (05) : 1833 - 1844
  • [29] Self-assembly of conformation-adaptive dihydrophenazine-based coordination cages
    Wu, Meng-Xiang
    Hong, Qiong-Yan
    Li, Minghui
    Jiang, Wei-Ling
    Huang, Bin
    Lu, Shuai
    Wang, Heng
    Yang, Hai-Bo
    Zhao, Xiao-Li
    Shi, Xueliang
    CHEMICAL COMMUNICATIONS, 2024, 60 (09) : 1184 - 1187
  • [30] Anticancer Activity and Cisplatin Binding Ability of Bis-Quinoline and Bis-lsoquinoline Derived [Pd2L4]4+ Metallosupramolecular Cages
    Vasdev, Roan A. S.
    Gaudin, Lachlan F.
    Preston, Dan
    Jogy, Jackmil P.
    Giles, Gregory
    Crowley, James D.
    FRONTIERS IN CHEMISTRY, 2018, 6
12345