The pre-reactive complex H2O...ClF identified in mixtures of water vapour and chlorine monofluoride by rotational spectroscopy

被引:32
作者
Cooke, SA
Cotti, G
Evans, CM
Holloway, JH
Legon, AC
机构
[1] UNIV EXETER,DEPT CHEM,EXETER EX4 4QD,DEVON,ENGLAND
[2] UNIV LEICESTER,DEPT CHEM,LEICESTER LE1 7RH,LEICS,ENGLAND
关键词
D O I
10.1039/cc9960002327
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A pre-reactive complex H2O ... ClF of planar (C-2 nu) or effectively planar (C-s) geometry is characterised for the first time in mixtures of water vapour and chlorine monofluoride through its rotational spectrum, as observed with a fast-mixing nozzle/Fourier-transform microwave spectrometer.
引用
收藏
页码:2327 / 2328
页数:2
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