Simple relationship between the properties of isotopic water

被引:44
作者
Vedamuthu, M
Singh, S
Robinson, GW
机构
[1] TEXAS TECH UNIV,DEPT CHEM,SUBPICOSECOND & QUANTUM RADIAT LAB,LUBBOCK,TX 79409
[2] TEXAS TECH UNIV,DEPT PHYS,SUBPICOSECOND & QUANTUM RADIAT LAB,LUBBOCK,TX 79409
关键词
D O I
10.1021/jp953268z
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In an earlier paper on this subject, it was conjectured that if temperatures of H2O and D2O are scaled according to their temperatures of maximum density, then the structural properties of these two liquids should be very closely the same. In this paper it is found that the idea is valid for the densities within the four decimal point experimental precision of the D2O data. If this structural effect is not taken into account, a comparison of properties, such as viscosities or self-diffusion coefficients, of isotopic liquid water would have a reduced meaning. Comparing data at the same temperature, as has traditionally been done, simply gives rise to misleading isotope effects.
引用
收藏
页码:3825 / 3827
页数:3
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