Structure and synthesis of nitrosoruthenium trans-diammines [Ru(NO)(NH3)2Cl3] and [Ru(NO)(NH3)2(H2O)Cl2]Cl•H2O

被引：19
|
作者：
Il'in, M. A. [1 ,2 ]
Emel'yanov, V. A. [1 ,2 ]
Baidina, I. A. [1 ]
机构：
[1] Russian Acad Sci, Siberian Div, AV Nikolaev Inst Inorgan Chem, Novosibirsk, Russia
[2] Novosibirsk State Univ, Novosibirsk, Russia
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2008年 / 49卷 / 06期
关键词：
ruthenium; nitroso complexes; ammine complexes; chloro complexes; single crystal X-ray diffraction; thermogravimetric analysis;
D O I：
10.1007/s10947-008-0183-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A DTA study of thermal decomposition of (NH4)(2)[Ru(NO)Cl-5] in helium atmosphere has been carried out, a synthetic procedure for preparation of the trans-diammine complex mer-[Ru(NO)(NH3)(2)Cl-3] (I) with yield similar to 70% has been developed. On re-crystallization of I from aqueous solution a trans-aquanitroso complex [Ru(NO)(NH3)(2)Cl-2(H2O)]Cl center dot H2O (II) has been isolated. The structures of the compounds have been determined by single crystal X-ray diffraction: space group Pbcn, a = 6.607(1) A... b = 11.255(2) A... c = 9.878(2) A... (I) and space group Ima2, a = 8.3032(3) A..., b = 8.0890(2) A..., c = 15.9192(5) A... II).
引用
收藏
页码：1090 / 1097
页数：8
相关论文
共 50 条
  • [21] Structure, synthesis, and thermal properties of trans-[Ru(NO)(NH3)4(SO4)]NO3·H2O
    A. N. Makhinya
    M. A. Il’in
    I. A. Baidina
    P. E. Plyusnin
    N. I. Alferova
    D. P. Pishchur
    Journal of Structural Chemistry, 2014, 55 : 311 - 318
  • [22] Structure, synthesis, and thermal properties of trans-[Ru(NO)(NH3)4(SO4)]NO3•H2O
    Makhinya, A. N.
    Il'in, M. A.
    Baidina, I. A.
    Plyusnin, P. E.
    Alferova, N. I.
    Pishchur, D. P.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2014, 55 (02) : 311 - 318
  • [23] COMPARISON OF THE RATES OF SUBSTITUTION IN [RU(NH3)(5)H2O](3+) AND [OS(NH3)(5)H2O](3+) BY HEXACYANO COMPLEXES - SUBSTITUTION COUPLED TO ELECTRON-TRANSFER
    POULOPOULOU, VG
    LI, ZW
    TAUBE, H
    INORGANICA CHIMICA ACTA, 1994, 225 (1-2) : 173 - 184
  • [24] Crystal structure of ammonium pentachloroaquaruthenate(III) (NH4)2[Ru(H2O)Cl5]
    Emel'yanov, V. A.
    Virovets, A. V.
    Baidina, I. A.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2008, 49 (03) : 566 - 569
  • [25] Crystal structure of ammonium pentachloroaquaruthenate(III) (NH4)2[Ru(H2O)Cl5]
    V. A. Emel’yanov
    A. V. Virovets
    I. A. Baidina
    Journal of Structural Chemistry, 2008, 49 : 566 - 569
  • [26] Crystal structure of [Pd(NH3)4]3[Ir(NO2)6]2•H2O
    Rybinskaya, A. A.
    Shusharina, E. A.
    Plyusnin, P. E.
    Shubin, Yu V.
    Korenev, S. V.
    Gromilov, S. A.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2011, 52 (04) : 816 - 819
  • [27] Crystal structure of [Pd(NH3)4]3[Ir(NO2)6]2·H2O
    A. A. Rybinskaya
    E. A. Shusharina
    P. E. Plyusnin
    Yu. V. Shubin
    S. V. Korenev
    S. A. Gromilov
    Journal of Structural Chemistry, 2011, 52 : 816 - 819
  • [28] Reaction of trans-[RuNO(NH3)4(OH)]Cl2 with nitric acid and synthesis of ammine(nitrato)nitrosoruthenium complexes
    E. V. Kabin
    V. A. Emel’yanov
    V. A. Vorob’yev
    N. I. Alferova
    S. V. Tkachev
    I. A. Baidina
    Russian Journal of Inorganic Chemistry, 2012, 57 : 1146 - 1153
  • [29] Reaction of trans-[RuNO(NH3)4(OH)]Cl2 with nitric acid and synthesis of ammine(nitrato)nitrosoruthenium complexes
    Kabin, E. V.
    Emel'yanov, V. A.
    Vorob'yev, V. A.
    Alferova, N. I.
    Tkachev, S. V.
    Baidina, I. A.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2012, 57 (08) : 1146 - 1153
  • [30] Synthesis and crystal structure of mer-nitroaquatriamminenitrosylruthenium(II) nitrate [RuNO(NH3)3(NO2)(H2O)](NO3)2
    Vorobyev, Vasily
    Kabin, Evgeniy V.
    Emelyanov, Vyacheslav A.
    Baidina, Iraida A.
    Korolkov, Ilya V.
    INORGANIC CHEMISTRY COMMUNICATIONS, 2016, 68 : 1 - 3
12345