Structure and synthesis of nitrosoruthenium trans-diammines [Ru(NO)(NH3)2Cl3] and [Ru(NO)(NH3)2(H2O)Cl2]Cl•H2O

被引：20
作者：
Il'in, M. A. [1 ,2 ]
Emel'yanov, V. A. [1 ,2 ]
Baidina, I. A. [1 ]
机构：
[1] Russian Acad Sci, Siberian Div, AV Nikolaev Inst Inorgan Chem, Novosibirsk, Russia
[2] Novosibirsk State Univ, Novosibirsk, Russia
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2008年 / 49卷 / 06期
关键词：
ruthenium; nitroso complexes; ammine complexes; chloro complexes; single crystal X-ray diffraction; thermogravimetric analysis;
D O I：
10.1007/s10947-008-0183-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A DTA study of thermal decomposition of (NH4)(2)[Ru(NO)Cl-5] in helium atmosphere has been carried out, a synthetic procedure for preparation of the trans-diammine complex mer-[Ru(NO)(NH3)(2)Cl-3] (I) with yield similar to 70% has been developed. On re-crystallization of I from aqueous solution a trans-aquanitroso complex [Ru(NO)(NH3)(2)Cl-2(H2O)]Cl center dot H2O (II) has been isolated. The structures of the compounds have been determined by single crystal X-ray diffraction: space group Pbcn, a = 6.607(1) A... b = 11.255(2) A... c = 9.878(2) A... (I) and space group Ima2, a = 8.3032(3) A..., b = 8.0890(2) A..., c = 15.9192(5) A... II).
引用
收藏
页码：1090 / 1097
页数：8
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