Selective oxidation of H2S in the presence of ammonia and water using Co3O4/SiO2 catalyst

被引:14
|
作者
Chun, SW [1 ]
Jang, JY [1 ]
Park, DW [1 ]
Woo, HC [1 ]
Chung, JS [1 ]
机构
[1] PUSAN NATL UNIV,DEPT CHEM ENGN,PUSAN 609735,SOUTH KOREA
关键词
selective oxidation; hydrogen sulfide; ammonia; water; catalyst;
D O I
10.1007/BF02706099
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The catalytic performance of some metal oxides in the selective oxidation of H2S in the stream containing water Vapor and ammonia was investigated in this study. Among the catalysts tested, Co3O4/SiO2 was the most promising catalyst for practical application. It showed very small amount of SO2 emission even in the presence of excess water and ammonia. The solid product formed in the reaction was a mixture of elemental sulfur, ammonium thiosulfate and ammonium sulfate.
引用
收藏
页码:216 / 218
页数:3
相关论文
共 50 条
  • [1] Selective oxidation of h2s in the presence of ammonia and water using co3o4/sio2 catalyst
    Sung Woo Chun
    Jae Yeol Jang
    Dae Won Park
    Hee Chul Woo
    Jong Shik Chung
    Korean Journal of Chemical Engineering, 1997, 14 : 216 - 218
  • [2] Selective Oxidation of Hydrogen Sulfide Containing Ammonia and Water Using Fe2O3/SiO2 Catalyst
    Kim, Moon-il
    Lee, Gu-Hwa
    Chun, Sung-Woo
    Park, Dae-Won
    KOREAN CHEMICAL ENGINEERING RESEARCH, 2012, 50 (03): : 398 - 402
  • [3] SiO2 supported Co3O4 catalyst for selective oxidation of cyclohexene with molecular oxygen
    Yogendra, Kamma
    Sitaramulu, Palli
    Nazeer, Silligandla
    Kumar, Palnati Manoj
    Reddy, Benjaram M.
    Rao, Tumula Venkateshwar
    BIOMASS CONVERSION AND BIOREFINERY, 2025, 15 (02) : 3027 - 3041
  • [4] Removal of hydrogen sulfide contained in smelt-off-gas by selective oxidation over Co3O4/SiO2 catalyst
    Park, DW
    Chun, SW
    Park, BK
    JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 2001, 34 (02) : 274 - 278
  • [5] Kinetic Study on the Selective Oxidation of H2S Containing Excess Water and Ammonia
    Dae-Kwang Park
    Young-Gu Cho
    Dae-Won Park
    Hee-Chul Woo
    Reaction Kinetics and Catalysis Letters, 2001, 74 : 57 - 66
  • [6] Kinetic study on the selective oxidation of H2S containing excess water and ammonia
    Park, DK
    Choe, YG
    Park, DW
    Woo, HC
    REACTION KINETICS AND CATALYSIS LETTERS, 2001, 74 (01): : 57 - 66
  • [7] Epoxidation of Styrene with Molecular Oxygen on Co3O4/SiO2 Catalyst
    Shen, Yangyi
    Zhu, Mingqiao
    Du, Jinpei
    Yang, Yangyang
    Tang, Yue
    ADVANCES IN CHEMICAL ENGINEERING, PTS 1-3, 2012, 396-398 : 1699 - 1702
  • [8] Selective oxidation of H2S to sulfur over CeO2-TiO2 catalyst
    Kang, Dong-Heon
    Kim, Moon-Il
    Park, Dae-Won
    KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2016, 33 (03) : 838 - 843
  • [9] Selective oxidation of cyclopentene to glutaraldehyde by H2O2 over the WO3/SiO2 catalyst
    Jin, RH
    Li, HX
    Deng, JF
    JOURNAL OF CATALYSIS, 2001, 203 (01) : 75 - 81
  • [10] Phase cooperation of V2O5 and Bi2O3 in the selective oxidation of H2S containing ammonia and water
    Cho, YG
    Hwang, BH
    Park, DW
    Woo, HC
    Chung, JS
    KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2002, 19 (04) : 611 - 616