Composite of Cu metal nanoparticles-multiwall carbon nanotubes-reduced graphene oxide as a novel and high performance platform of the electrochemical sensor for simultaneous determination of nitrite and nitrate

In the present research, we aimed to fabricate a novel electrochemical sensor based on Cumetalnanoparticles on the multiwall carbon nanotubes-reduced graphene oxide nanosheets (Cu/MWCNT/RGO) for individual and simultaneous determination of nitrite and nitrate ions. The morphology of the prepared nanocomposite on the surface of glassy carbon electrode (GCE) was characterized using various methods including scanning electron microscopy (SEM), atomic force microscopy (AFM), and electrochemical impedance spectroscopy. Under optimal experimental conditions, themodified GCE showed excellent catalytic activity toward the electro-reduction of nitrite and nitrate ions (pH =3.0) with a significant increase in cathodic peak currents in comparison with the unmodified GCE. By square wave voltammetry (SWV) the fabricated sensor demonstrated wide dynamic concentration ranges from 0.1 to 75 mu M with detection limits (3S(b)/m) of 30 nM and 20 nM method for nitrite and nitrate ions, respectively. Furthermore, the applicability of the proposed modified electrode was demonstrated by measuring the concentration of nitrite and nitrate ions in the tap and mineral waters, sausages, salami, and cheese samples. (C) 2016 Elsevier B.V. All rights reserved.