Treating birch wood with a switchable 1,8-diazabicyclo-[5.4.0]-undec-7-ene-glycerol carbonate ionic liquid

被引：28

作者：

Anugwom, Ikenna ^{[1
]}

Maki-Arvela, Paivi ^{[1
]}

Virtanen, Pasi ^{[1
]}

Willfor, Stefan ^{[2
]}

Damlin, Pia ^{[3
]}

Hedenstrom, Mattias ^{[4
]}

Mikkola, Jyri-Pekka ^{[1
]}

机构：

[1] Abo Akad Univ, Lab Ind Chem & React Engn, Proc Chem Ctr, FI-20500 Turku, Finland

[2] Abo Akad Univ, Lab Wood & Paper Chem, Proc Chem Ctr, FI-20500 Turku, Finland

[3] Univ Turku, Dept Chem, FI-20014 Turku, Finland

[4] Umea Univ, Computat Life Sci Cluster CLIC, Dept Chem, Chem Biol Ctr, SE-90187 Umea, Sweden

来源：

HOLZFORSCHUNG | 2012年 / 66卷 / 07期

关键词：

fractionation of lignocellulose; recovery of dissolved lignocelluloses; reuse of spent SIL; switchable ionic liquids (SILs); treatment time; DISSOLUTION; CELLULOSE; LIGNIN;

D O I：

10.1515/hf-2011-0226

中图分类号：

S7 [林业];

学科分类号：

0829 ; 0907 ;

摘要：

The suitability of a new switchable ionic liquid (SIL) has been investigated as a solvent for fractionation of lignocellulosic materials. SIL was prepared from inexpensive chemicals, e. g., glycerol, CO2, and 1,8-diazabicyclo-[5.4.0]-undec-7-ene (DBU). Fresh Nordic birch wood (B. pendula) was treated with the SIL for a time period of 1-5 days at 100 degrees C and under atmospheric pressure. Upon SIL treatment, at best, 57 % of the hemicelluloses were dissolved and 50 % of lignins were dissolved from the native birch. The slightly fibrillated SIL treated chips contained about 55 % cellulose. Up to 76 % of the recovered species removed from the spent SIL liquor was originating from hemicelluloses, mainly from xylan. The spent SILs were reused for fresh wood dissolution in four consecutive cycles and each time the wood dissolution efficiency was similar. SILs could offer affordable (easy-to-synthesize) solvent systems for partial elimination of hemicelluloses and lignin from wood. SILs can also be prepared in-situ and on-site.

引用

页码：809 / 815

页数：7

共 26 条

[1] Selective extraction of hemicelluloses from spruce using switchable ionic liquids [J].

Anugwom, I. ;

Maki-Arvela, P. ;

Virtanen, P. ;

Willfor, S. ;

Sjoholm, R. ;

Mikkola, J. -P. .

CARBOHYDRATE POLYMERS, 2012, 87 (03) :2005-2011

[2] Switchable Ionic liquids (SILs) based on glycerol and acid gases [J].

Anugwom, Ikenna ;

Maki-Arvela, Paivi ;

Virtanen, Pasi ;

Damlin, Pia ;

Sjoholm, Rainer ;

Mikkola, Jyri-Pekka .

RSC ADVANCES, 2011, 1 (03) :452-457

[3] Monitoring and Analyzing Process Streams Towards Understanding Ionic Liquid Pretreatment of Switchgrass (Panicum virgatum L.) [J].

Arora, Rohit ;

Manisseri, Chithra ;

Li, Chenlin ;

Ong, Markus D. ;

Scheller, Henrik Vibe ;

Vogel, Kenneth ;

Simmons, Blake A. ;

Singh, Seema .

BIOENERGY RESEARCH, 2010, 3 (02) :134-145

[4] The role of solid state 13C NMR spectroscopy in studies of the nature of native celluloses [J].

Atalla, RH ;

VanderHart, DL .

SOLID STATE NUCLEAR MAGNETIC RESONANCE, 1999, 15 (01) :1-19

[5] Structural FTIR analysis and thermal characterisation of lyocell and viscose-type fibres [J].

Carrillo, A ;

Colom, X ;

Sunol, JJ ;

Saurina, J .

EUROPEAN POLYMER JOURNAL, 2004, 40 (09) :2229-2234

[6] Structural analysis of photodegraded wood by means of FTIR spectroscopy [J].

Colom, X ;

Carrillo, F ;

Nogués, F ;

Garriga, P .

POLYMER DEGRADATION AND STABILITY, 2003, 80 (03) :543-549

[7]

D'andola G., 2008, WO Patent Application No, Patent No. [2008043837 (A1), 2008043837, WO 2008043837]

[8]

Fort DA, 2007, GREEN CHEM, V9, P63, DOI 10.1039/B607614A

[9] Green chemistry - Reversible nonpolar-to-polar solvent [J].

Jessop, PG ;

Heldebrant, DJ ;

Li, XW ;

Eckert, CA ;

Liotta, CL .

NATURE, 2005, 436 (7054) :1102-1102

[10] Dissolution of wood in ionic liquids [J].

Kilpelainen, Ilkka ;

Xie, Haibo ;

King, Alistair ;

Granstrom, Mari ;

Heikkinen, Sami ;

Argyropoulos, Dimitris S. .

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2007, 55 (22) :9142-9148

← 1 2 3 →