Synthesis and optical properties of a naphthalimide dimer

被引：2

作者：

Li, Xiaochuan ^{[1
]}

Ma, Wenjing ^{[1
]}

Sun, Jiao ^{[1
]}

Mei, Kuan ^{[1
]}

Yang, Min ^{[1
]}

Xie, Fuli ^{[1
]}

Zhu, Kaijuan ^{[1
]}

Jiang, Wenjuan ^{[1
]}

Li, Yajuan ^{[1
]}

Kim, Hyungjoo ^{[2
]}

Son, Younga ^{[2
]}

机构：

[1] Henan Normal Univ, Minist Educ, Key Lab Green Chem Media & React, Coll Chem & Environm Sci, 46 Jianshe Rd, Xinxiang 453007, Henan, Peoples R China

[2] Chungnam Natl Univ, Dept Adv Organ Mat, Daejeon 305764, South Korea

来源：

PHYSICA STATUS SOLIDI C: CURRENT TOPICS IN SOLID STATE PHYSICS, VOL 9, NO 12 | 2012年 / 9卷 / 12期

基金：

新加坡国家研究基金会; 中国国家自然科学基金;

关键词：

naphthalimide derivative; chromophores; fluorescence; Stokes shift; intramolecular charge transfer; FLUORESCENCE;

D O I：

10.1002/pssc.201200269

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

In this contribution, a new naphthalimide dimer with A-pi-D-pi-A framework was synthesized efficiently and well characterized. Its spectral properties were investigated. Significant features, such as strong solid and liquid fluorescence, usual large Stokes shift were discussed in terms of its electronic structures. In addition, it is soluble in common organic solvent and stable at ambient conditions. Optimized molecular structure shows the twisted molecular conformation, which leads to its narrow solid emission. Frontier orbital calculation indicates effective excited-state intramolecular charge transfer. [GRAPHICS] Optimized molecular structure of naphthalimide dimer (left) and its fluorescence excited by 405 nm laser. (C) 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

引用

页码：2452 / 2455

页数：4

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