Crystal structure of [(C6H4)P][Ni(B9C2H11)2]•CCl4

被引：2

作者：

Polyanskaya, T. M. ^{[1
]}

Drozdova, M. K. ^{[1
]}

Volkov, V. V. ^{[1
]}

机构：

[1] Russian Acad Sci, AV Nikolaev Inst Inorgan Chem, Siberian Div, Novosibirsk, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2008年 / 49卷 / 03期

关键词：

metal derivative of ortho-carborane(12); nickel(III) bisdicarbollyl anion; tetraphenylphosphonium; synthesis; molecular and crystal structure;

D O I：

10.1007/s10947-008-0076-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new compound containing the tetraphenylphosphonium cation and the nickel(III) bisdicarbollyl anion, [(C6H5)(4)P][Ni(B9C2H11)(2)]center dot CCl4, was synthesized and investigated by XRD at room temperature (295 K). Crystal data: C29H42B18PCl4Ni, M=816.69, monoclinic, space group P2/c; unit cell parameters a = 13.5873(6) angstrom, b = 7.1475(2) angstrom, c = 20.7829(8) angstrom, beta = 94.4595(13)degrees, V = 2012.2(2) angstrom(3), Z = 2, d(calc) = 1.348 g/cm(3). The structure was solved by direct and Fourier methods and refined by the full-matrix least squares method in an anisotropic (isotropic for H) approximation to the final R-1 = 0.0466 for 3055 I-hkl >= 2 sigma(I) of 23,655 reflections collected and 5618 independent I-hkl (Bruker X8 APEX diffractometer lambda MoK alpha).

引用

页码：560 / 565

页数：6

共 17 条

[1] SIR97:: a new tool for crystal structure determination and refinement [J].

Altomare, A ;

Burla, MC ;

Camalli, M ;

Cascarano, GL ;

Giacovazzo, C ;

Guagliardi, A ;

Moliterni, AGG ;

Polidori, G ;

Spagna, R .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1999, 32 :115-119

[2]

Bruker AXS Inc, 2004, APEX2 (Version 1.08), SAINT (Version 7.03), and SADABS (Version 2.11)

[3] CRYSTAL STRUCTURE AND MOLECULAR GEOMETRY OF TETRAPHENYLPHOSPHONIUM PI-CYCLOPENTADIENYLBIS-(1,2-DICYANOETHYLENE-1,2-DITHIOLATO)MOLYBDENUM, PH4P+PI-C5H5)MO(S2C2(CN)2)2- [J].

CHURCHILL, MR ;

COOKE, J .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1970, (12) :2046-+

[4] CRYSTAL STRUCTURE OF TETRAPHENYLPHOSPHONIUM TRICHLORO-(CIS-BUT-2-EN-1,4-DIOL)PLATINUM(II) [J].

COLAPIETRO, M ;

ZAMBONELLI, L .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1971, B 27 (APR15) :734-+

[5]

DUNKS GB, 1975, BORON HYDRIDE CHEM, P383

[6] CRYSTAL STRUCTURE OF TETRAPHENYLPHOSPHONIUM BIS(TETRACYANOQUINODIMETHANIDE) [J].

GOLDSTEIN, P ;

SEFF, K ;

TRUEBLOOD, KN .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1968, B 24 :778-+

[7] CRYSTAL AND MOLECULAR-STRUCTURE OF TETRAMETHYLAMMONIUM 3,3'-COMMO-BIS[1,2-DICARBA-3-NICKELACLOSO-DODECABORATE](1-) [J].

HANSEN, FV ;

HAZELL, RG ;

HYATT, C ;

STUCKY, GD .

ACTA CHEMICA SCANDINAVICA, 1973, 27 (04) :1210-1218

[8] PI-DICARBOLLYL DERIVATIVES OF TRANSITION METALS . METALLOCENE ANALOGS [J].

HAWTHORNE, MF ;

YOUNG, DC ;

ANDREWS, TD ;

HOWE, DV ;

PILLING, RL ;

PITTS, AD ;

REINTJES, M ;

WARREN, LF ;

WEGNER, PA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (04) :879-+

[9] Electronic and crystal structure of (N-CH3-2,2′-bipyridinium)(dodecahydro-dicarba-nido-undecaborate) [J].

Il'inchik, E. A. ;

Polyanskaya, T. M. ;

Volkov, V. V. .

JOURNAL OF STRUCTURAL CHEMISTRY, 2007, 48 (02) :300-309

[10]

[Надолинный B.А. Nadolinnyi V.A.], 2005, [Координационная химия, Koordinatsionnaya khimiya], V31, P403

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