Fe3O4 NANOPARTICLES AS AN EFFICIENT AND MAGNETICALLY RECOVERABLE CATALYST FOR FRIEDEL-CRAFTS ACYLATION REACTION IN SOLVENT-FREE CONDITIONS

被引：40
|
作者：
Hoseini, S. Jafar [1 ]
Nasrabadi, Hasan [1 ]
Azizi, Mahboobeh [1 ]
Beni, Alireza Salimi [1 ]
Khalifeh, Reza [2 ]
机构：
[1] Univ Yasuj, Dept Chem, Fac Sci, Yasuj 74831, Iran
[2] Shiraz Uunivers Technol, Dept Chem, Shiraz, Iran
来源：
SYNTHETIC COMMUNICATIONS | 2013年 / 43卷 / 12期
关键词：
Catalyst; Fe3O4; nanoparticles; Friedel-Crafts acylation; heterogenous catalysts; solvent free; IRON-OXIDE;
D O I：
10.1080/00397911.2012.663048
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Application of Fe3O4 nanoparticles (NPs) as a robust, very efficient, and magnetically recoverable catalyst was investigated in Friedel-Crafts acylation (FCA) of ferrocene and aromatic compounds. This reaction was performed with acid chlorides in solvent-free conditions at room temperature. The catalyst was easily separated by an external magnetic field from the reaction mixture. The separated catalyst was recycled for several consecutive runs without appreciable loss of its catalytic activity.
引用
收藏
页码：1683 / 1691
页数：9
相关论文
共 50 条
  • [41] Effects of acyl donor type, catalyst type, and reaction conditions on the activity and selectivity of Friedel-Crafts acylation
    Adi Wolfson
    Rao P. Madhusudhan
    Ayelet Shapira-Tchelet
    Miron V. Landau
    Chemical Papers, 2009, 63 : 291 - 297
  • [42] Effects of acyl donor type, catalyst type, and reaction conditions on the activity and selectivity of Friedel-Crafts acylation
    Wolfson, Adi
    Madhusudhan, Rao P.
    Shapira-Tchelet, Ayelet
    Landau, Miron V.
    CHEMICAL PAPERS, 2009, 63 (03) : 291 - 297
  • [43] Three-component Friedel-Crafts reaction of indoles, glyoxylate, and amine under solvent-free and catalyst-free conditions - Synthesis of (3-indolyl)glycine derivatives
    Zhao, JL
    Liu, L
    Zhang, HB
    Wu, YC
    Wang, D
    Chen, YJ
    SYNLETT, 2006, (01) : 96 - 100
  • [44] Ytterbium triflate catalysed Friedel-Crafts reaction using carboxylic acids as acylating reagents under solvent-free conditions
    Jin, Can
    Li, Jie
    Su, Weike
    JOURNAL OF CHEMICAL RESEARCH, 2009, (10) : 607 - 611
  • [45] Reduction of nitroarenes by magnetically recoverable nitroreductase immobilized on Fe3O4 nanoparticles
    Zhang, Qikun
    Yu, Liping
    Liu, Baoliang
    Li, Fulin
    Tang, Bo
    SCIENTIFIC REPORTS, 2020, 10 (01)
  • [46] Preparation of a magnetically recoverable biocatalyst support on monodisperse Fe3O4 nanoparticles
    Zhang, Qikun
    Han, Xiaotong
    Tang, Bo
    RSC ADVANCES, 2013, 3 (25) : 9924 - 9931
  • [47] Reduction of nitroarenes by magnetically recoverable nitroreductase immobilized on Fe3O4 nanoparticles
    Qikun Zhang
    Liping Yu
    Baoliang Liu
    Fulin Li
    Bo Tang
    Scientific Reports, 10
  • [48] EFFECT OF COMPONENTS AND REACTION CONDITIONS ON FRIEDEL-CRAFTS ACYLATION .3. ACYLATION OF BENZYL-TYPE AMINES
    YAKUBOV, AP
    BELENKII, LI
    GOLDFARB, YL
    ZHURNAL ORGANICHESKOI KHIMII, 1971, 7 (03): : 525 - &
  • [49] An efficient and green pathway for continuous Friedel-Crafts acylation over α-Fe2O3 and CaCO3 nanoparticles prepared in the microreactors
    Fang, Zheng
    He, Wei
    Tu, Tao
    Lv, Niuniu
    Qiu, Chuanhong
    Li, Xin
    Zhu, Ning
    Wan, Li
    Guo, Kai
    CHEMICAL ENGINEERING JOURNAL, 2018, 331 : 443 - 449
  • [50] Ln(OTf)(3)-LiClO4 as reusable catalyst system for Friedel-Crafts acylation
    Kawada, A
    Mitamura, S
    Kobayashi, S
    CHEMICAL COMMUNICATIONS, 1996, (02) : 183 - 184
12345