Fe3O4 NANOPARTICLES AS AN EFFICIENT AND MAGNETICALLY RECOVERABLE CATALYST FOR FRIEDEL-CRAFTS ACYLATION REACTION IN SOLVENT-FREE CONDITIONS

被引：40
|
作者：
Hoseini, S. Jafar [1 ]
Nasrabadi, Hasan [1 ]
Azizi, Mahboobeh [1 ]
Beni, Alireza Salimi [1 ]
Khalifeh, Reza [2 ]
机构：
[1] Univ Yasuj, Dept Chem, Fac Sci, Yasuj 74831, Iran
[2] Shiraz Uunivers Technol, Dept Chem, Shiraz, Iran
来源：
SYNTHETIC COMMUNICATIONS | 2013年 / 43卷 / 12期
关键词：
Catalyst; Fe3O4; nanoparticles; Friedel-Crafts acylation; heterogenous catalysts; solvent free; IRON-OXIDE;
D O I：
10.1080/00397911.2012.663048
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Application of Fe3O4 nanoparticles (NPs) as a robust, very efficient, and magnetically recoverable catalyst was investigated in Friedel-Crafts acylation (FCA) of ferrocene and aromatic compounds. This reaction was performed with acid chlorides in solvent-free conditions at room temperature. The catalyst was easily separated by an external magnetic field from the reaction mixture. The separated catalyst was recycled for several consecutive runs without appreciable loss of its catalytic activity.
引用
收藏
页码：1683 / 1691
页数：9
相关论文
共 50 条
  • [1] Mild and efficient solvent-free Friedel-Crafts acylation of reserpine
    Begum, Sabira
    Zehra, Syeda Qamar
    Siddiqui, Bina S.
    SYNTHETIC COMMUNICATIONS, 2006, 36 (21) : 3203 - 3224
  • [2] Fe3O4 Nanoparticles as an Efficient and Magnetically Recoverable Catalyst for the Synthesis of α,β-Unsaturated Heterocyclic and Cyclic Ketones under Solvent-Free Conditions
    Alishiri, Tooba
    Oskooei, Hossein A.
    Heravi, Majid M.
    SYNTHETIC COMMUNICATIONS, 2013, 43 (24) : 3357 - 3362
  • [3] Synthesis of Bis(indolyl)methanes Using Fe3O4 Nanoparticle as a Robust, Efficient and Magnetically Recoverable Catalyst Under Solvent-Free Conditions
    Willig, Julia C. M.
    Amaral, Alexandra A.
    Rafique, Jamal
    Saba, Sumbal
    Valiati, Stefany
    de Oliveira, Isadora M.
    Stefani, Helio A.
    Manarin, Flavia
    Botteselle, Giancarlo, V
    REVISTA VIRTUAL DE QUIMICA, 2018, 10 (05) : 1591 - 1606
  • [4] Magnetically recoverable γ-Fe2O3 nanoparticles as a highly active catalyst for Friedel-Crafts benzoylation reaction under ultrasound irradiation
    Phuong Hoang Tran
    Thuy-Duy Thi Nguyen
    Tram-Anh Thi Tu
    Thach Ngoc Le
    ARABIAN JOURNAL OF CHEMISTRY, 2020, 13 (01) : 290 - 297
  • [5] Fe3O4 Nanoparticles as an Efficient and Magnetically Recoverable Catalyst for the Synthesis of 3,4-Dihydropyrimidin-2(1H)-ones under Solvent-Free Conditions
    Nasr-Esfahani, Masoud
    Hoseini, S. Jafar
    Mohammadi, Fatemeh
    CHINESE JOURNAL OF CATALYSIS, 2011, 32 (09) : 1484 - 1489
  • [6] Fe3O4 nanoparticles as an efficient and magnetically recoverable catalyst for the synthesis of 3,4-dihydropyrimidin-2(1H)-ones under solvent-free conditions
    Nasr-Esfahani, Masoud
    Hoseini, S. Jafar
    Mohammadi, Fatemeh
    Chinese Journal of Catalysis, 2011, 32 (9-10): : 1484 - 1489
  • [7] A rapid, mild, efficient, and solvent-free friedel-crafts acylation of N-acetyltetrahydroharmine
    Begum, S
    Hassan, SI
    Siddiqui, BS
    SYNTHETIC COMMUNICATIONS, 2005, 35 (01) : 23 - 39
  • [8] K2FeZrP3O12 AS AN EFFICIENT CATALYST FOR FRIEDEL-CRAFTS BENZYLATION UNDER SOLVENT-FREE CONDITIONS
    Sheikhan, Nafisehsadat
    Hajipour, Abdol R.
    Acta Chemica Iasi, 2016, 24 (02) : 102 - 111
  • [9] Zinc mediated friedel-crafts acylation in solvent-free conditions under microwave irradiation
    Paul, S
    Nanda, P
    Gupta, R
    Loupy, A
    SYNTHESIS-STUTTGART, 2003, (18): : 2877 - 2881
  • [10] Nano Fe3O4 as magnetically recyclable catalyst for the synthesis of α-aminophosphonates in solvent-free conditions
    Reddy, B. V. Subba
    Krishna, A. Siva
    Ganesh, A. V.
    Kumar, G. G. K. S. Narayana
    TETRAHEDRON LETTERS, 2011, 52 (12) : 1359 - 1362
12345