Synthesis of silver nanoparticles deposited on silica by γ-irradiation and preparation of PE/Ag nano compound masterbatches

被引:8
|
作者
Thi Kim Lan Nguyen [1 ]
Thuy Ai Trinh Nguyen [2 ]
Van Phu Dang [1 ]
Ngoc Duy Nguyen [1 ]
Anh Quoc Le [1 ]
Quoc Hien Nguyen [1 ]
机构
[1] Vietnam Atom Energy Inst, Res & Dev Ctr Radiat Technol, Linh Xuan Ward, Ho Chi Minh City, Vietnam
[2] Vietnam Natl Univ Ho Chi Minh City, Ho Chi Minh City Univ Technol, Ho Chi Minh City, Vietnam
关键词
silver nanoparticles; silica; gamma ray; polyethylene; ANTIBACTERIAL ACTIVITY; REDUCTION;
D O I
10.1088/2043-6262/4/4/045004
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Silver nanoparticles (AgNPs) deposited on silica were synthesized by gamma Co-60 irradiation of Ag+ dispersion in silica/ethanol/water mixture (9/80/20:w/v/v). The reduction of Ag+ is occurred by hydrated electron (e(aq)(-)) and hydrogen atom (H-center dot) generated during radiolysis of ethanol/water. The conversion doses (Ag+ -> Ag-0) were determined by UV-Vis spectroscopy. The synthesized AgNPs/silica were characterized by transmission electron microscopy (TEM) and x-ray diffraction (XRD), which showed the size of AgNPs to be in the range of 5-40 nm for Ag+ concentrations from 5 to 20 mM. Masterbatches of PE/AgNPs/silica compound with silver content from 250 to 1000 mg kg(-1) were also prepared. These masterbatches can be suitably used for various applications such as antimicrobial food containers and packing films, etc.
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页数:4
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