Here we report a new path to study single molecule electron transfer dynamics by coupling scanning fluorescence microscopy with a potentiostat via a conventional electrochemical cell to enable single-molecule fluorescence spectroelectrochemistry of cresyl violet in aqueous solution, demonstrating that the single-molecule fluorescence intensity of cresyl violet is modulated synchronously with the cyclic voltammetric potential scanning.
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Department of Biochemistry and Molecular Biology, Mayo Clinic Rochester, Rochester, MN
Department of Physiology and Biomedical Engineering, Mayo Clinic Rochester, Rochester, MNDepartment of Biochemistry and Molecular Biology, Mayo Clinic Rochester, Rochester, MN
Burghardt T.P.
Ajtai K.
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Department of Biochemistry and Molecular Biology, Mayo Clinic Rochester, Rochester, MNDepartment of Biochemistry and Molecular Biology, Mayo Clinic Rochester, Rochester, MN