Five metal-organic frameworks based on 5-(pyridine-3-yl)pyrazole-3-carboxylic acid ligand: Syntheses, structures and properties

被引:28
作者
Cheng, Jiajia [1 ]
Wang, Shimin [2 ]
Shi, Zhan [1 ]
Sun, Huan [1 ]
Li, Baojun [1 ]
Wang, Miaomiao [1 ]
Li, Muyang [3 ]
Li, Jinpeng [1 ]
Liu, Zhongyi [1 ]
机构
[1] Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Henan, Peoples R China
[2] Henan Inst Engn, Coll Mat & Chem Engn, Zhengzhou 451191, Peoples R China
[3] Zhengzhou Univ, Zhengzhou 450001, Henan, Peoples R China
关键词
Polymer; Crystal structure; Fluorescence properties; Magnetic properties; CD(II) COORDINATION POLYMERS; MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURES; PHOTOLUMINESCENT PROPERTIES; SPECTROSCOPIC PROPERTIES; LUMINESCENT PROPERTIES; POLYCARBOXYLATE ACIDS; COPPER(II) COMPOUNDS; COMPLEXES; DICARBOXYLATE;
D O I
10.1016/j.ica.2016.08.001
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Five new polymers based on 5-(pyridine-3-yl)pyrazole-3-carboxylic acid (H(2)ppca), namely, [Cd-2(ppca) (bix)(SO4)](n) (1), {[Cd(HPPca)(2)]center dot H2O}(n) (2), {[Mn(Hppca)(2)]center dot H2O}(n) (3), [Zn(2()ppca)(2)](n) (4) and [Cu(ppca)](n) (5) have been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction, elemental analyses and IR spectroscopy. Structural analyses reveal that polymer 1 possesses a 2-fold interpenetrating three-dimensional (3D) framework. Polymers 2 and 3 display 4-connected 2D frameworks, while polymer 4 features a (3,3)-connected topology with the Schlafli symbol (4.8.10). 5 exhibits a 2D structure with the Schlafli symbol (4.8(2)). Furthermore, the fluorescence properties of the five polymers are also investigated in the solid state, showing the fluorescence signal changes in comparing with that of free ligand mbbz. Polymer 5 with square pyramid geometry (tau(cu1), 0.069) implies that there is strong antiferromagnetic interactions between two adjacent Cu1C and Cul, and the magnetic interactions are mainly transferred by the bridging N,N-triazole ligands. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:86 / 94
页数:9
相关论文
共 58 条
[1]   SYNTHESIS, STRUCTURE, AND SPECTROSCOPIC PROPERTIES OF COPPER(II) COMPOUNDS CONTAINING NITROGEN SULFUR DONOR LIGANDS - THE CRYSTAL AND MOLECULAR-STRUCTURE OF AQUA[1,7-BIS(N-METHYLBENZIMIDAZOL-2'-YL)-2,6-DITHIAHEPTANE]COPPER(II) PERCHLORATE [J].
ADDISON, AW ;
RAO, TN ;
REEDIJK, J ;
VANRIJN, J ;
VERSCHOOR, GC .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (07) :1349-1356
[2]   Syntheses, Crystal Structures, and Magnetic Properties of Metal-Organic Hybrid Materials of Co(II) Using Flexible and Rigid Nitrogen-Based Ditopic Ligands as Spacers [J].
Ahmad, Musheer ;
Sharma, Mamsh K. ;
Das, Raja ;
Poddar, Pankai ;
Bharadwaj, Parimal K. .
CRYSTAL GROWTH & DESIGN, 2012, 12 (03) :1571-1578
[3]  
Blatov V. A., 2006, IUCr CompComm Newsletter, V7, P4, DOI DOI 10.1039/B807165A
[4]  
Blatov V. A., 2009, TOPOS, a multipurpose crystallochemical analysis with the program package
[5]   A building block approach to the synthesis of organic-inorganic oxide materials:: the hydrothermal synthesis and network structure of [{Ni4(tpypyz)3}{Mo5O15(O3PCH2CH2PO3)}2]•23H2O (tpypyz = tetra-2-pyridylpyrazine) [J].
Burkholder, E ;
Golub, V ;
O'Connor, CJ ;
Zubieta, J .
CHEMICAL COMMUNICATIONS, 2003, (17) :2128-2129
[6]   Ligand-Isomerism Controlled Structural Diversity of Zn(II) and Cd(II) Coordination Polymers from Mixed Dipyridyladipoamide and Benzenedicarboxylate Ligands [J].
Cheng, Pei-Chi ;
Kuo, Po-Ting ;
Liao, Yu-Hung ;
Xie, Ming-Yuan ;
Hsu, Wayne ;
Chen, Jhy-Der .
CRYSTAL GROWTH & DESIGN, 2013, 13 (02) :623-632
[7]   Solid State Coordination Chemistry of the Copper(II)/Pyridyl- and Pyrazine-Tetrazolate/Sulfate System [J].
Darling, Kari ;
Ouellette, Wayne ;
Prosvirin, Andrey ;
Freund, Steven ;
Dunbar, Kim R. ;
Zubieta, Jon .
CRYSTAL GROWTH & DESIGN, 2012, 12 (05) :2662-2672
[8]   Antiferromagnetic Mixed-Valence Cu(I)-Cu(II) Two-Dimensional Coordination Polymers Constructed by Double Oximato Bridged Cu(II) Dimers and CuISCN Based One-Dimensional Anionic Chains [J].
Das, Lakshmi Kanta ;
Diaz, Carmen ;
Ghosh, Ashutosh .
CRYSTAL GROWTH & DESIGN, 2015, 15 (08) :3939-3949
[9]   Ancillary Ligands Dependent Structural Diversity of A Series of Metal Organic Frameworks Based on 3,5-Bis(3carboxyphenyl)pyridine [J].
Fan, Liming ;
Zhang, Xiutang ;
Sun, Zhong ;
Zhang, Wei ;
Ding, Yuanshuai ;
Fan, Weiliu ;
Sun, Liming ;
Zhao, Xian ;
Lei, Han .
CRYSTAL GROWTH & DESIGN, 2013, 13 (06) :2462-2475
[10]   Dimetallic complexes derived from a novel dinucleating chelating symmetric triazole ligand;: crystal structure, magnetic properties and ESR study of bis[μ-3,5-diacetylamino-1,2,4-triazolato-O′,N1,N2,O"]bis[(nitrato)(aqua)copper(II)] [J].
Ferrer, S ;
van Koningsbruggen, PJ ;
Haasnoot, JG ;
Reedijk, J ;
Kooijman, H ;
Spek, AL ;
Lezama, L ;
Arif, AM ;
Miller, JS .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (23) :4269-4276