Antiferromagnetic ordering through a hydrogen-bonded network in the molecular solid CuF2(H2O)2(3-chloropyridine)

被引：15

作者：

Lapidus, Saul H. ^{[1
]}

Manson, Jamie L. ^{[2
]}

Park, Hyunsoo ^{[1
]}

Clement, Alexander J. ^{[1
]}

Ghannadzadeh, Saman ^{[3
]}

Goddard, Paul ^{[3
]}

Lancaster, Tom ^{[4
]}

Moeller, Johannes S. ^{[3
]}

Blundell, Stephen J. ^{[3
]}

Telling, Mark T. F. ^{[5
,6
]}

Kang, Jinhee ^{[7
]}

Whangbo, Myung-Hwan ^{[7
]}

Schlueter, John A. ^{[1
]}

机构：

[1] Argonne Natl Lab, Div Mat Sci, Argonne, IL 60439 USA

[2] Eastern Washington Univ, Dept Chem & Biochem, Cheney, WA 99004 USA

[3] Univ Oxford, Dept Phys, Clarendon Lab, Oxford OX1 3PU, England

[4] Univ Durham, Ctr Phys Mat, Durham DH1 3LE, England

[5] Rutherford Appleton Lab, ISIS Facil, Chilton OX11 0QX, Oxon, England

[6] Univ Oxford, Dept Mat, Oxford OX1 3PH, England

[7] N Carolina State Univ, Dept Chem, Raleigh, NC 27695 USA

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 05期

基金：

美国国家科学基金会; 英国工程与自然科学研究理事会;

关键词：

MAGNETIC MODEL SYSTEMS; PYRAZINE; PHYSICS; PYZ;

D O I：

10.1039/c2cc37444g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

CuF2(H2O)(2)(3-chloropyridine) possesses a five-coordinate Cu2+ center with a slightly distorted trigonal bypyramidal coordination geometry. Strong intermolecular F center dot center dot center dot H-O hydrogen bonds enable the formation of 2D layers and provide the primary magnetic exchange path that leads to the stabilization of long-range antiferromagnetic (AFM) order below T-N = 2.1 K.

引用

页码：499 / 501

页数：3

共 13 条

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