Straightforward Synthetic Access to gem-Diaurated and Digold σ,π-Acetylide Species

被引：72

作者：

Gomez-Suarez, Adrian ^{[1
]}

Dupuy, Stephanie ^{[1
]}

Slawin, Alexandra M. Z. ^{[1
]}

Nolan, Steven P. ^{[1
]}

机构：

[1] Univ St Andrews, EaStCHEM Sch Chem, St Andrews KY16 9ST, Fife, Scotland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 03期

基金：

英国工程与自然科学研究理事会;

关键词：

gold; N-heterocyclic carbenes; reactive intermediates; structure elucidation; X-ray diffraction; GOLD-CATALYZED SYNTHESIS; TERMINAL ALKYNES; DUAL-ACTIVATION; BORONIC ACIDS; COMPLEXES; TRANSMETALATION; CYCLOISOMERIZATION; VINYLIDENES; INSERTIONS; REACTIVITY;

D O I：

10.1002/anie.201208234

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The more the merrier: Following previous investigations on the synthesis of organogold complexes by using [Au(IPr)(OH)], a high-yielding straightforward methodology for the synthesis of gem-diaurated and σ,π-acetylide species via a dinuclear gold hydroxide complex [{Au(IPr)}2(μ-OH)] [BF4] (see scheme) has now been developed. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：938 / 942

页数：5

共 58 条

[1]

[Anonymous], 2009, Angew. Chem

[2]

[Anonymous], 2012, ANGEW CHEM

[3] Gold-catalyzed decorations of arenes and heteroarenes with C-C multiple bonds [J].

Bandini, Marco .

CHEMICAL SOCIETY REVIEWS, 2011, 40 (03) :1358-1367

[4] New organogold(I) complexes: Synthesis, structure, and dynamic behavior of the polynuclear organogold diphenylmethane and diphenylethane derivatives [J].

Baukova, TV ;

Kuzmina, LG ;

Oleinikova, NA ;

Lemenovskii, DA ;

Blumenfeld, AL .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 530 (1-2) :27-38

[5] Gold-mediated C-H bond functionalisation [J].

Boorman, Tanya C. ;

Larrosa, Igor .

CHEMICAL SOCIETY REVIEWS, 2011, 40 (04) :1910-1925

[6] Mechanistic Analysis of Gold(I)-Catalyzed Intramolecular Allene Hydroalkoxylation Reveals an Off-Cycle Bis(gold) Vinyl Species and Reversible C-O Bond Formation [J].

Brown, Timothy J. ;

Weber, Dieter ;

Gagne, Michel R. ;

Widenhoefer, Ross A. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (22) :9134-9137

[7] Cationic Gold(I) π-Complexes of Terminal Alkynes and Their Conversion to Dinuclear σ,π-Acetylide Complexes [J].

Brown, Timothy J. ;

Widenhoefer, Ross A. .

ORGANOMETALLICS, 2011, 30 (21) :6003-6009

[8] Gold-catalyzed cycloisomerization of 1,5-allenynes via dual activation of an ene reaction [J].

Cheong, Paul Ha-Yeon ;

Morganelli, Philip ;

Luzung, Michael R. ;

Houk, K. N. ;

Toste, F. Dean .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (13) :4517-4526

[9] Gold-catalyzed propargylic substitutions: Scope and synthetic developments [J].

Debleds, Olivier ;

Gayon, Eric ;

Vrancken, Emmanuel ;

Campagne, Jean-Marc .

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 2011, 7 :866-877

[10] N-Heterocyclic Carbenes in Late Transition Metal Catalysis [J].

Diez-Gonzalez, Silvia ;

Marion, Nicolas ;

Nolan, Steven P. .

CHEMICAL REVIEWS, 2009, 109 (08) :3612-3676

← 1 2 3 4 5 6 →