Exploring the role of Sodium dodecyl sulphate in presence of 2thioureidobenzoxazole as enhancer of corrosion inhibition of mild steel in 2M HCl solution

被引：1

作者：

Murthy, Ram ^{[1
]}

Krishna, Kanala Raghava ^{[2
]}

Sundaresan, C. N. ^{[1
]}

机构：

[1] Sri Sathya Sai Inst Higher Learning, Brindavan Campus, Bengaluru 560067, India

[2] HP Green R&D Ctr, Dept Crude & Fuels Res Lab, Bangalore 560117, Karnataka, India

来源：

INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE | 2022年 / 17卷 / 09期

关键词：

Corrosion inhibition; mild steel; Impedance; Adsorption;

D O I：

10.20964/2022.09.43

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

In the current communication, we report the role of sodium do-decyl sulphate (SDS) as the corrosion inhibition enhancer for 2-thioureidobenzoxazole (BOT) on mild steel (MS) in 2M Hydrochloric acid electrolyte. Though, 2-thioureidobenzoxazole shows limited inhibition due of the presence of oxygen atom, addition of small quantity of SDS enhances the inhibition by 10-fold. Electrochemical impedance spectroscopy, Tafel measurements and weight loss studies were used in the current work. The variation of temperature on the inhibition efficiency of SDS+BOT on MS surface was explored. The Gibbs free energy of adsorption values showed that inhibition process is spontaneous. Langmuir adsorption was prevalent and the morphological characterization was carried out using scanning electron microscope which indicated the role of SDS as a versatile performance enhancer for BOT. This combination, act as an anodic mixed type inhibitor.

引用

页数：13

共 16 条

[1] Synergistic inhibition effect of novel counterion-coupled surfactant based on rice bran oil and halide ion on the C-steel corrosion in molar sulphuric acid: Experimental and computational approaches [J].

Abd El-Lateef, Hany M. ;

Khalaf, Mai M. .

JOURNAL OF MOLECULAR LIQUIDS, 2021, 331

[2]

Ahmed S. K., 2019, INT J IND CHEM

[3] Molecular structural aspects of organic corrosion inhibitors: Experimental and computational insights [J].

Chauhan, Dheeraj Singh ;

Verma, Chandrabhan ;

Quraishi, M. A. .

JOURNAL OF MOLECULAR STRUCTURE, 2021, 1227

[4] Inhibitory influence of cationic Gemini surfactant on the dissolution rate of N80 carbon steel in 15% HCl solution [J].

Deyab, M. A. ;

Mohsen, Q. .

SCIENTIFIC REPORTS, 2021, 11 (01)

[5] Novel macrocyclic cationic surfactants: Synthesis, experimental and theoretical studies of their corrosion inhibition activity for carbon steel and their antimicrobial activities [J].

El-Tabei, A. S. ;

Hegazy, M. A. ;

Bedair, A. H. ;

El Basiony, N. M. ;

Sadeq, M. A. .

JOURNAL OF MOLECULAR LIQUIDS, 2022, 345

[6] Corrosion inhibition of mild steel by 2-(2-methoxybenzylidene) hydrazine-1-carbothioamide in hydrochloric acid solution: Experimental measurements and quantum chemical calculations [J].

Ferkous, Hana ;

Djellali, Souad ;

Sahraoui, Rachid ;

Benguerba, Yacine ;

Behloul, Hamza ;

Cukurovali, Alaaddin .

JOURNAL OF MOLECULAR LIQUIDS, 2020, 307

[7] Corrosion inhibition of carbon steel in hydrochloric acid: Elucidating the performance of an imidazoline-based surfactant [J].

Kousar, K. ;

Walczak, M. S. ;

Ljungdahl, T. ;

Wetzel, A. ;

Oskarsson, H. ;

Restuccia, P. ;

Ahmad, E. A. ;

Harrison, N. M. ;

Lindsay, R. .

CORROSION SCIENCE, 2021, 180

[8] 5-AMINO-3H-1,2,4-DITHIAZOLE-3-THIONE AS A SYNTHON - NEW SYNTHESIS OF 2-THIOUREIDOBENZHETEROAZOLES [J].

KRISHNASWAMY, NR ;

SUNDARESAN, CN ;

NAMBISAN, PNK ;

SANDYA, K .

HETEROATOM CHEMISTRY, 1994, 5 (5-6) :567-569

[9] Corrosion Inhibition of Mild Steel in 2M HCI by a Schiff Base Derivative [J].

Kumari, Preethi P. ;

Rao, Suma A. ;

Shetty, Prakash .

INTERNATIONAL CONFERENCE ON ADVANCES IN MANUFACTURING AND MATERIALS ENGINEERING (ICAMME 2014), 2014, 5 :499-507

[10] Novel cationic Gemini ester surfactant as an efficient and eco-friendly corrosion inhibitor for carbon steel in HCl solution [J].

Mao, Taoyan ;

Huang, Haiming ;

Liu, Dantong ;

Shang, Xiaoqin ;

Wang, Weiliang ;

Wang, Liming .

JOURNAL OF MOLECULAR LIQUIDS, 2021, 339

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