Synthesis and Crystal Structure of Coordination Polymer [Sc2(HOCH2CH2OH)4(tFBDC)3] • 2HOCH2CH2OH

被引：5
|
作者：
Cheplakova, A. M. [1 ,2 ]
Samsonenko, D. G. [1 ,2 ]
Fedin, V. P. [1 ,2 ]
机构：
[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia
[2] Novosibirsk State Univ, Novosibirsk, Russia
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2019年 / 60卷 / 02期
基金：
俄罗斯基础研究基金会;
关键词：
scandium complexes; metal-organic coordination polymer; tetrafluoroterephthalic acid; crystal structure; FRAMEWORKS;
D O I：
10.1134/S002247661902015X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The heating of a mixture of as-precipitated scandium hydroxide and tetrafluoroterephthalic acid in ethylene glycol leads to the formation of the complex [Sc-2(HOCH2CH2OH)(4)(tFBDC)(3)]2HOCH(2)CH(2)OH (tFBDC(2-) = tetrafluoroterephthalate) (1). According to the X-ray data, compound 1 is a chain coordination polymer. Sc(III) cations and tFBDC(2-) anions form double chains (ribbons). The coordination number of Sc(III) is completed to seven by ethylene glycol molecules acting as chelate ligands. There is a complex system of hydrogen bonding interactions induced by oxygen atoms of carboxylic groups of perfluorinated ligands and coordinated and lattice ethylene glycol.
引用
收藏
页码：289 / 293
页数：5
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