Immobilized Ru Clusters in Nanosized Mesoporous Zirconium Silica for the Aqueous Hydrogenation of Furan Derivatives at Room Temperature

被引：98

作者：

Chen, Jiazhi ^{[1
,2
]}

Lu, Fang ^{[1
]}

Zhang, Junjie ^{[1
,2
]}

Yu, Weiqiang ^{[1
]}

Wang, Feng ^{[1
]}

Gao, Jin ^{[1
]}

Xu, Jie ^{[1
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China

[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

来源：

CHEMCATCHEM | 2013年 / 5卷 / 10期

基金：

中国国家自然科学基金;

关键词：

biomass; cluster compounds; hydrogenation; mesoporous materials; ruthenium; METAL-CLUSTERS; RUTHENIUM CATALYSTS; AEROBIC OXIDATION; GOLD CLUSTERS; SUPPORT; NANOPARTICLES; CONVERSION; EFFICIENT; SIZE;

D O I：

10.1002/cctc.201300316

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ru lonesome tonight? Immobilized ruthenium clusters (50Ru atoms) in nanosized mesoporous zirconium silica were synthesized by using an impregnation method starting from an aqueous solution of RuCl3. The Ru cluster catalysts were thermally stable at 500°C and showed remarkable activity for the hydrogenation of furan derivatives in water at room temperature under 5bar hydrogen pressure. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：2822 / 2826

页数：5

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