Self-assembly of linear rod-coil multiblock copolymers

被引：8
作者：
Xia, Ying-dong [1 ]
Chen, Ji-zhong [1 ]
Shi, Tong-fei [1 ]
An, Li-jia [1 ]
机构：
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
来源：
CHINESE JOURNAL OF POLYMER SCIENCE | 2013年 / 31卷 / 09期
基金：
中国国家自然科学基金;
关键词：
Rod-coil multiblock copolymer; Self-assembly; Self-consistent-field lattice; LATERALLY-TETHERED NANORODS; BLOCK-COPOLYMERS; BEHAVIOR; PHASE;
D O I：
10.1007/s10118-013-1322-8
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The self-assembly of the linear rod-coil multiblock copolymers is studied by applying self-consistent-field lattice techniques in a three-dimensional (3D) space. Compared to the copolymer with one rod, the copolymer with more rods (m (rod) a parts per thousand yen 2) exhibits rich order-order phase transitions with increasing temperature, where the ordered morphology changes from strips to perforated lamellae and finally to lamellae. In addition, taking the copolymer with m (rod) = 2 as a representative, we further study the effects of the volume fractions of the rods, the spacer coils and the end coils on the phase behaviors respectively, by which the detailed self-assembled mechanism of the linear rod-coil multiblock copolymers is revealed. Our results are expected to provide guidance for the design of the rod-coil materials.
引用
收藏
页码：1242 / 1249
页数：8
相关论文
共 29 条
  • [1] Soluble oligoaramide precursors - A novel class of building blocks for rod-coil architectures
    Abbel, R
    Frey, H
    Schollmeyer, D
    Kilbinger, AFM
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (07) : 2170 - 2176
  • [2] Microphase separation and liquid-crystalline ordering of rod-coil copolymers
    AlSunaidi, A.
    den Otter, W. K.
    Clarke, J. H. R.
    [J]. JOURNAL OF CHEMICAL PHYSICS, 2009, 130 (12)
  • [3] Well-defined fullerene-containing homopolymers and diblock copolymers with high fullerene content and their use for solution-phase and bulk organization
    Ball, ZT
    Sivula, K
    Fréchet, JMJ
    [J]. MACROMOLECULES, 2006, 39 (01) : 70 - 72
  • [4] Extension of rod-coil multiblock copolymers and the effect of the helix-coil transition
    Buhot, A
    Halperin, A
    [J]. PHYSICAL REVIEW LETTERS, 2000, 84 (10) : 2160 - 2163
  • [5] Study of self-assembly of symmetric coil-rod-coil ABA-type triblock copolymers by self-consistent field lattice method
    Chen, Ji-Zhong
    Zhang, Cheng-Xiang
    Sun, Zhao-Yan
    An, Li-Jia
    Tong, Zhen
    [J]. JOURNAL OF CHEMICAL PHYSICS, 2007, 127 (02)
  • [6] Self-assembly of rod-coil-rod ABA-type triblock copolymers
    Chen, Ji-Zhong
    Sun, Zhao-Yan
    Zhang, Cheng-Xiang
    An, Li-Jia
    Tong, Zhen
    [J]. JOURNAL OF CHEMICAL PHYSICS, 2008, 128 (07)
  • [7] Self-assembled smectic phases in rod-coil block copolymers
    Chen, JT
    Thomas, EL
    Ober, CK
    Mao, GP
    [J]. SCIENCE, 1996, 273 (5273) : 343 - 346
  • [8] A novel self-consistent-field lattice model for block copolymers
    Chen, JZ
    Zhang, CX
    Sun, ZY
    Zheng, YS
    An, LJ
    [J]. JOURNAL OF CHEMICAL PHYSICS, 2006, 124 (10)
  • [9] Facile synthesis of well-defined block copolymers containing regioregular poly(3-hexyl thiophene) via anionic macroinitiation method and their self-assembly behavior
    Dai, Chi-An
    Yen, Wei-Che
    Lee, Yi-Huan
    Ho, Chun-Chi
    Su, Wei-Fang
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (36) : 11036 - +
  • [10] Supramolecular self-assembly and opto-electronic properties of semiconducting block copolymers
    de Boer, B
    Stalmach, U
    van Hutten, PF
    Melzer, C
    Krasnikov, VV
    Hadziioannou, G
    [J]. POLYMER, 2001, 42 (21) : 9097 - 9109
123