AC conduction of Ba1-xCaxTiO3 and BZT-BCTx

被引:4
作者
Nguyen Van Khien [1 ]
Than Trong Huy [4 ]
Le Van Hong [2 ,3 ]
机构
[1] Thai Nguyen Univ, Thai Nguyen, Vietnam
[2] VAST, Inst Mat Sci, Hanoi, Vietnam
[3] Duy Tan Univ, Da Nang, Vietnam
[4] Phu Xuan Univ, Hue, Vietnam
关键词
Ferroelectrics; Dielectrics; Substitution effect; XRD; AC conduction; PIEZOELECTRIC CERAMICS; DIELECTRIC-PROPERTIES; RELAXATION;
D O I
10.1016/j.physb.2017.04.017
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Ba1-xCaxTiO3 (BCTx), (x = 0.0-0.3) and Ba0.8Zr0.2TiO3-Ba1-xCaxTiO3 (BZT-BCTx), (x=0.15-0.35) were fabricated by the solid state reaction method. Phase structure of the material samples was identified by X-ray diffraction. The impedance versus frequency in a range of 100 Hz to 2.5 MHz was measured for all the samples at room temperature. AC conductivity versus frequency of the BCTx and BZT-BCTx was evaluated and fitted by using the extended Universal Dielectric Response (UDR) equations. The fitting results were discussed in detail and shown that the localized reorientation polarization-based mechanism is most contributed in BCTx matrial samples. Basically both two the hopping polaron and polarization mechanisms play roles in BZT-BCTx material samples. In contrary the short-range polaron hopping is dominated in ac conductivity of BZT-BCTx material samples in low frequency range.
引用
收藏
页码:126 / 129
页数:4
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