Application of multi-walled carbon nanotubes modified with boron oxide nanoparticles in electrochemistry

被引:8
|
作者
Tsierkezos, Nikos G. [1 ]
Ritter, Uwe [1 ]
Thaha, Yudi. Nugraha [1 ]
Downing, Clive [2 ]
机构
[1] Ilmenau Univ Technol, Inst Chem & Biotechnol, Dept Chem, D-98693 Ilmenau, Germany
[2] Univ Dublin Trinity Coll, Adv Microscopy Lab, CRANN, Dublin 2, Ireland
关键词
Boron oxide nanoparticles; Electrochemical analysis; Multi-walled carbon nanotubes; Scanning electron microscopy; Transmission electron microscopy; POTASSIUM FERRICYANIDE; VOLTAMMETRIC DETERMINATION; MODIFIED ELECTRODE; PASTE ELECTRODE; PARACETAMOL; ACETAMINOPHEN; DOPAMINE; SUPERCAPACITORS; REDUCTION; TRANSPORT;
D O I
10.1007/s11581-015-1496-x
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Multi-walled carbon nanotubes modified with boron oxide nanoparticles (B-MWCNTs) were synthesized onto oxidized silicon substrate upon decay of ethyl alcohol and boric acid in presence of catalyst by means of chemical vapor deposition technique. The B-MWCNTs were characterized using scanning electron microscopy and transmission electron microscopy in combination with electron energy loss spectroscopy. The B-MWCNTs were electrochemically studied using ferrocyanide/ferricyanide, [Fe(CN)(6)](3-/4-) redox system in potassium chloride solution. Furthermore, the response of B-MWCNTs towards oxidation of acetaminophen (AC) to N-acetyl-p-quinoneimine (NAPQI) was also studied in phosphate buffer solution (pH 7.0). The effect of boron oxide nanoparticles on electrochemical response of B-MWCNTs was probed. Therefore, B-MWCNTs were treated with hydrochloric acid for elimination of boron oxide nanoparticles and their electrochemical response towards [Fe(CN)(6)](3-/4-) and AC/NAPQI redox systems was studied. The results demonstrate the strong influence of boron oxide nanoparticles on electrochemical response of B-MWCNTs.
引用
收藏
页码:3087 / 3095
页数:9
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