New aspect of nucleophilic reactivity of tertiary phosphine oxides. R3PO-POCl3 binary system

被引：5

作者：

Kazantseva, MV ^{[1
]}

Timokhin, BV ^{[1
]}

Rokhin, AV ^{[1
]}

Blazhev, DG ^{[1
]}

Golubin, AI ^{[1
]}

Rybakova, YV ^{[1
]}

机构：

[1] Irkutsk State Univ, Inst Petr & Coal Chem Synth, Irkutsk, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2001年 / 71卷 / 08期

关键词：

Oxide; Alcohol; Chloride; Phosphorus; Binary System;

D O I：

10.1023/A:1013264726682

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of tertiary phosphine oxides with phosphorus oxychloride was found to give triorganylphosphonium dichlorophosphates R3PCl+PO2Cl2- rather than phosphorylphosphonium salts R3P OPOCl2. Mixtures of the reagents, called binary system, possess a considerable synthetic potential. They are capable of converting alcohols to the corresponding alkyl chlorides.

引用

页码：1233 / 1235

页数：3