Oxidative coupling of methane in a solid oxide membrane reactor

被引：26

作者：

Guo, XM ^{[1
]}

Hidajat, K ^{[1
]}

Ching, CB ^{[1
]}

Chen, HF ^{[1
]}

机构：

[1] TIANJIN UNIV,DEPT CHEM ENGN,TIANJIN 300072,PEOPLES R CHINA

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 1997年 / 36卷 / 09期

关键词：

D O I：

10.1021/ie9607006

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The oxidative coupling of methane (OCM) has been studied using the 1 wt % Sr/La2O3-Bi2O3-Ag-YSZ solid oxide membrane reactor. The effects of oxygen flux, temperature and feed concentration on the performance of oxidative coupling of methane reaction have been investigated. Two mathematical models based on well-mixed flow (CSTM) or plug flow (PFM) in the reactor have been developed to describe the behavior of the solid oxide membrane reactors. The simulation results show good agreement with experimental data. However, the simulation results of the CSTM fit experimental data much better than that of PFM over a broad range of experimental conditions. The simulation results also show it is very important to match reaction conditions and reactor parameters.

引用

页码：3576 / 3582

页数：7

共 50 条

[1] Oxidative coupling of methane in a solid oxide fuel cell reactor [J].

Jiang, Y ;

Yentekakis, IV ;

Makri, M ;

Vayenas, CG .

PROCEEDINGS OF THE FIFTH INTERNATIONAL SYMPOSIUM ON SOLID OXIDE FUEL CELLS (SOFC-V), 1997, 97 (40) :235-243

[2] Oxidative coupling of methane in solid oxide fuel cell tubular membrane reactor with high ethylene yield [J].

Liu, Kefeng ;

Zhao, Jing ;

Zhu, Di ;

Meng, Fei ;

Kong, Fanhua ;

Tang, Yongchun .

CATALYSIS COMMUNICATIONS, 2017, 96 :23-27

[3] SELECTIVE OXIDATIVE COUPLING OF METHANE WITH MEMBRANE REACTOR [J].

NOZAKI, T ;

YAMAZAKI, O ;

OMATA, K ;

FUJIMOTO, K .

CHEMICAL ENGINEERING SCIENCE, 1992, 47 (9-11) :2945-2950

[4] OXIDATIVE COUPLING OF METHANE USING A MEMBRANE REACTOR [J].

OMATA, K ;

HASHIMOTO, S ;

TOMINAGA, H ;

FUJIMOTO, K .

APPLIED CATALYSIS, 1989, 52 (1-2) :L1-L4

[5] Oxidative coupling of methane to ethylene: Development of membrane reactor [J].

Zein, SHS ;

Mohamed, AR ;

Zabidi, NAM ;

Bhatia, S .

ADVANCES IN MALAYSIAN ENERGY RESEARCH 2000, 2001, :317-328

[6] Methane Oxidative Coupling: Synthesis of Membrane Reactor Networks [J].

Godini, H. R. ;

Jaso, S. ;

Xiao, Shengnan ;

Arellano-Garcia, H. ;

Omidkhah, M. ;

Wozny, G. .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2012, 51 (22) :7747-7761

[7] STUDIES ON THE CERAMIC MEMBRANE REACTOR FOR OXIDATIVE COUPLING OF METHANE [J].

HE Ren-Jin(Department of Chemistry Jinan University Guangzhou ;

Guangdong 510632)MA Yi-Hua(Department of Chemical Engineering Worcester Polytechnic InstituteWorcester ;

MA 01609-228O USA) .

Journal of Natural Gas Chemistry , 1996, (04) :306-319

[8] SIMULATION OF A CATALYTIC MEMBRANE REACTOR FOR OXIDATIVE COUPLING OF METHANE [J].

CHENG, S ;

SHUAI, X .

AICHE JOURNAL, 1995, 41 (06) :1598-1601

[9] Oxidative coupling of methane in a modified γ-alumina membrane reactor [J].

Lu, YP ;

Dixon, AG ;

Moser, WR ;

Ma, YH .

CHEMICAL ENGINEERING SCIENCE, 2000, 55 (21) :4901-4912

[10] OXIDE-ION TRANSPORT FOR SELECTIVE OXIDATIVE COUPLING OF METHANE WITH NEW MEMBRANE REACTOR [J].

NOZAKI, T ;

FUJIMOTO, K .

AICHE JOURNAL, 1994, 40 (05) :870-877

← 1 2 3 4 5 →