A facile "click" approach to functionalised metallosupramolecular architectures

被引:65
|
作者
Lewis, James E. M. [1 ]
McAdam, C. John [1 ]
Gardiner, Michael G. [2 ]
Crowley, James D. [1 ]
机构
[1] Univ Otago, Dept Chem, Dunedin, New Zealand
[2] Univ Tasmania, Sch Chem, Hobart, Tas, Australia
关键词
SPIN-CROSSOVER BEHAVIOR; ORGANOPLATINUM(II) METALLACYCLES; HEXAGONAL PRISMS; DRUG-DELIVERY; COMPLEXES; CHEMISTRY; HOSTS; CONSTRUCTION; DISCRETE; HELICATE;
D O I
10.1039/c3cc41209a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Herein we describe a CuAAC "click" methodology for exo-functionalisation of Pd2L4 metallosupramolecular architectures. The potentially coordinating 1,2,3-triazole does not affect formation of the desired discrete complexes, nor does this external functional decoration affect the cisplatin-binding ability of the interior cavity of the assembly.
引用
收藏
页码:3398 / 3400
页数:3
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